Origin of the α-effect in nucleophilic substitution reactions of y-substituted phenyl benzoates with butane-2,3-dione monoximate and z-substituted phenoxides: Ground-state destabilization vs. transition-state stabilization

Bulletin of the Korean Chemical Society

Volumn 30, Issue 12, 2009, Pages 2913-2917

  Kim, Mi Sun ^a   Min, Se Won ^a   Seo, Jin A ^a   Um, Ik Hwan ^a  

^a Ewha Womans University   (South Korea)

Author keywords

Concerted mechanism; Ground state destabilization; Solvent effect; The effect; Transition state stabilization

Indexed keywords

CONCERTED MECHANISM; HAMMETT PLOTS; LEAVING GROUPS; LINEAR CORRELATION; NUCLEOPHILIC SUBSTITUTION REACTIONS; PHENYL BENZOATES; RATE-DETERMINING STEP; SCATTERED POINTS; SECOND-ORDER RATE CONSTANTS; SOLVENT EFFECTS; TRANSITION-STATE;

BUTANE; CATALYSIS; GROUND STATE; LIQUEFIED PETROLEUM GAS; NUCLEOPHILES; RESPIRATORY MECHANICS; STABILIZATION; SUBSTITUTION REACTIONS;

RATE CONSTANTS;

EID: 76649134435     PISSN: 02532964     EISSN: 12295949     Source Type: Journal    
DOI: 10.5012/bkcs.2009.30.12.2913     Document Type: Article

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