Effects on the reactivity by changing the electrophilic center from C=O to C=S: Contrasting reactivity of hydroxide, p-chlorophenoxide, and butan-2,3-dione monoximate in DMSO/H2O mixtures

Chemistry - A European Journal

Volumn 15, Issue 4, 2009, Pages 1011-1017

  Um, Ik Hwan ^a   Han, Jeong Yoon ^a   Buncel, Erwin ^b  

^a Ewha Womans University   (South Korea)

^b QUEEN S UNIVERSITY   (Canada)

Author keywords

Electrophilic addition; Enthalpy of solution; Kinetics; Medium effect; Polarizability

Indexed keywords

ENTHALPY; MIXTURES; NUCLEOPHILES; RATE CONSTANTS; SOLVENTS;

ELECTROPHILIC ADDITION; ENTHALPY OF SOLUTION; KINETICS; MEDIUM EFFECT; POLARIZABILITY;

DIMETHYL SULFOXIDE;

EID: 58449117639     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200801534     Document Type: Article

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