Reactions of α-nucleophiles with alkyl chlorides: Competition between SN2 and E2 mechanisms and the gas-phase α-effect

Journal of the American Chemical Society

Volumn 131, Issue 23, 2009, Pages 8227-8233

  Villano, Stephanie M ^a   Eyet, Nicole ^a   Lineberger, W Carl ^a   Bierbaum, Veronica M ^a  

^a NONE

Author keywords

[No Author keywords available]

Indexed keywords

ADDITIONAL REACTIONS; ALKYL CHLORIDES; ANALOGOUS REACTIONS; DEUTERIUM KINETIC ISOTOPE EFFECT; ENHANCED REACTIVITY; ETHYL CHLORIDE; FLOWING AFTERGLOWS; GASPHASE; INTRINSIC PROPERTY; ION-DIPOLE COMPLEXES; KINETIC ISOTOPE EFFECTS; METHYL CHLORIDES; NUCLEOPHILIC SUBSTITUTIONS; ORGANIC MECHANISMS; SELECTED ION FLOW TUBES; SOLVENT EFFECTS; TRANSITION STATE;

CARRIER MOBILITY; COMPETITION; DEUTERIUM; NEGATIVE IONS; RATE CONSTANTS;

CHLORINE COMPOUNDS;

ALKYL GROUP; ANION; CHLORIDE; CHLOROETHANE; ION; ISOTOPE; METHYL CHLORIDE; NUCLEOPHILE;

ARTICLE; DIPOLE; GAS; PHASE TRANSITION; SOLVENT EFFECT; SUBSTITUTION REACTION;

EID: 67650561149     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9012084     Document Type: Article

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