Aminolysis of 2,4-dinitrophenyl and 3,4-dinitrophenyl 2- thiophenecarboxylates: Effect of ortho-nitro group on reactivity and mechanism

Bulletin of the Korean Chemical Society

Volumn 29, Issue 8, 2008, Pages 1459-1463

  Seo, Jin A ^a   Chun, Sun Mee ^a,b   Um, Ik Hwan ^a  

^a Ewha Womans University   (South Korea)

^b Daihan Ink Co Ltd   (South Korea)

Author keywords

Aminolysis; Br nsted type plot; ortho effect; Reaction mechanism; Steric hindrance

Indexed keywords

AMINES; CHEMICAL REACTIONS; DIMETHYL SULFOXIDE; RATE CONSTANTS;

AMINOLYSIS; MICROSCOPIC RATE CONSTANTS; ORTHO EFFECT; RATE DETERMINING STEP; REACTION MECHANISM; SECOND-ORDER RATE CONSTANTS; STERIC HINDRANCES; TETRAHEDRAL INTERMEDIATES;

REACTION INTERMEDIATES;

EID: 50449110073     PISSN: 02532964     EISSN: 12295949     Source Type: Journal    
DOI: 10.5012/bkcs.2008.29.8.1459     Document Type: Article

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