Evidence to support the hypothesis that promoting vibrations enhance the rate of an enzyme catalyzed H-tunneling reaction

Journal of the American Chemical Society

Volumn 131, Issue 47, 2009, Pages 17072-17073

  Pudney, Christopher R ^a   Hay, Sam ^a   Levy, Colin ^a   Pang, Jiayun ^a,b   Sutcliffe, Michael J ^a,b   Leys, David ^a   Scrutton, Nigel S ^a  

^a UNIVERSITY OF MANCHESTER   (United Kingdom)

^b UNIVERSITY OF MANCHESTER   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

DONOR-ACCEPTOR DISTANCE; DRIVING FORCES; HYDRIDE TRANSFERS; PENTAERYTHRITOL TETRANITRATE; TRANSFER REACTION; TRANSITION STATE THEORIES; TUNNELING REACTION; VIBRATIONAL MODES;

WIND TUNNELS;

TUNNELING (EXCAVATION);

FLAVINE MONONUCLEOTIDE; OXIDOREDUCTASE; PENTAERYTHRITOL TETRANITRATE REDUCTASE; PROTON; REDUCED NICOTINAMIDE ADENINE DINUCLEOTIDE; REDUCED NICOTINAMIDE ADENINE DINUCLEOTIDE PHOSPHATE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; ENZYME ACTIVITY; HYPOTHESIS; MOLECULAR DYNAMICS; PRESSURE; PROTON TRANSPORT; REACTION ANALYSIS; SYNTHESIS; TEMPERATURE DEPENDENCE; VIBRATION;

BIOCATALYSIS; ENZYMES; FLAVIN MONONUCLEOTIDE; KINETICS;

EID: 72249089538     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja908469m     Document Type: Article

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