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105
-
-
70449677650
-
-
note
-
4) pristine assembly, we can see a broad distribution with a maximum peak at around. 300 nm under the same preparation method. In Scheme 2A (TEM), the large flake assemblies are likely attributable to ZnP(Py)4 moieties, whereas particle shapes are composed, of fullerene moieties.
-
-
-
-
106
-
-
70449685156
-
-
note
-
n] according to the corresponding 'IEM images (SI: Figure S2). This result is similar to the DLS result.
-
-
-
-
107
-
-
70449691157
-
-
60Ph = ∼3.5:1.
-
60Ph = ∼3.5:1.
-
-
-
-
108
-
-
70449665336
-
-
note
-
4 rod: H, 2.02%; C, 84.01%.
-
-
-
-
109
-
-
70449683546
-
-
The intense XRD peak at ∼30° may be attributable to the interactive structure between ZnP(Py)4 and fullerene in Figure 3c and d.
-
The intense XRD peak at ∼30° may be attributable to the interactive structure between ZnP(Py)4 and fullerene in Figure 3c and d.
-
-
-
-
110
-
-
70449697028
-
-
Because of thermal decomposition of molecules at high temperature and residual CTAB surfactants within the rod assembly, it may be difficult to perform the clear quantitative discussion.
-
Because of thermal decomposition of molecules at high temperature and residual CTAB surfactants within the rod assembly, it may be difficult to perform the clear quantitative discussion.
-
-
-
-
111
-
-
0000207034
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35348944807
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-
-
70449682895
-
-
note
-
1ZnP* moiety (see Figures 7 and 8).
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The various light-absorption cross sections toward nanorods are possible considering the nanorod orientation on film (Figure 9B). On the other hand, the exciten diffusion length of organic dyes such as porphyrins is generally limited (ca. several nm). Considering these points and quenching properties of time-resolved measurements (fluorescence lifetimes and transient absorption), we can propose that light-absorbed D/A interfacial, layers contribute mainly to the immediate charge-separation process. See the reference paper for exciton diffusion of porphyrins:Huijser, A.; Savenije, T. L; Meskers, S. C. L; Vermeulen, M. J. W.; Siebbeles, L. D. A. J. Am. Chem. Soc. 2008, 130, 12496.
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(2008)
Am. Chem. Soc.
, vol.130
, pp. 12496
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Huijser, A.1
Savenije, T.L.2
Meskers, S.C.L.3
Vermeulen, M.J.W.4
Siebbeles, L.D.A.J.5
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121
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70449697027
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On the basis of the discussion in ref 46, the broad photoresponse in the 600-700 nm region may contribute to charge separation via the excited state of fullerene assemblies.
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On the basis of the discussion in ref 46, the broad photoresponse in the 600-700 nm region may contribute to charge separation via the excited state of fullerene assemblies.
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124
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(c) Di Carlo, A.; Piacenza, F.; Bolognesi, A.; Stadiober, B.; Maresch, H. Appl.Phys. Lett, 2005, 86, 263501.
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(2005)
Appl.Phys. Lett
, vol.86
, pp. 263501
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Di Carlo, A.1
Piacenza, F.2
Bolognesi, A.3
Stadiober, B.4
Maresch, H.5
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