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70349105406
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The blurred shadow around a carbon structure is a trace of vapored DMF solvent.
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The blurred shadow around a carbon structure is a trace of vapored DMF solvent.
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75
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33749162833
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n sample in TGA agree well with that of other nanohybrid systems composed of nanocarbons and porphyrins; see: ref. [26b] and a
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n sample in TGA agree well with that of other nanohybrid systems composed of nanocarbons and porphyrins; see: ref. [26b] and a) S. Campidelli, C. Sooambar, E. L. Diz, C. EhIi, D. M. Guldi, M. Prato, /. Am. Chem. Soc. 2006, 128, 12544;
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77
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70349086866
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4): C, 90.57; H, 2.07; N, 1.13; found: C, 90.36; H, 2.06; N, 1.13. This indicates that one porphyrin is attached per 640 carbon atoms.
-
4): C, 90.57; H, 2.07; N, 1.13; found: C, 90.36; H, 2.06; N, 1.13. This indicates that one porphyrin is attached per 640 carbon atoms.
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78
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0035939713
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The some positions on the edge and/or sidewall of a cup-shaped nanocarbon were hydrogenated by the electron-transfer reduction, see
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The some positions on the edge and/or sidewall of a cup-shaped nanocarbon were hydrogenated by the electron-transfer reduction, see S. Pekker, J.-P. Salvetat, E. Jakab, J.-M. Bonard, L. Forró, /. Phys. Chem. B 2001, 105, 7938.
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70349122435
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n was also absorbed a light at 426 nm. Thus, the actual ratio of fluorescence quenching that can be estimated from absorption ratio is about 80%.
-
n was also absorbed a light at 426 nm. Thus, the actual ratio of fluorescence quenching that can be estimated from absorption ratio is about 80%.
-
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84
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0001508451
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For fluorescence lifetime of a meso-substituted porphyrin, see: a
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For spectroscopic characterization of photogenerated porphyrin redical cation in nanocarbon-based hybrid system, ref. [18b, 20b], see
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For spectroscopic characterization of photogenerated porphyrin redical cation in nanocarbon-based hybrid system, ref. [18b, 20b], see:
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95
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70349131894
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The CS lifetime was also determined from the decay time profiles at 750 nm as 0.64 ± 0.01ms.
-
The CS lifetime was also determined from the decay time profiles at 750 nm as 0.64 ± 0.01ms.
-
-
-
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96
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70349140838
-
-
n solution was irradiated with a high-pressure mercury lamp (X > 380 nm) equipped with a UV-light cut filter accompanied by rapidly falling temperature.
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n solution was irradiated with a high-pressure mercury lamp (X > 380 nm) equipped with a UV-light cut filter accompanied by rapidly falling temperature.
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97
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0000374858
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3 was prepared according to the literature; see
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3+; see
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For the reduction potential of carbon nanotube; see
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For the reduction potential of carbon nanotube; see: M. MelleFranco, M. Marcaccio, D. Paolucci, F. Paolucci, V. Georgakilas, D. M. Guldi, M. Prato, F. Zerbetto, J. Am. Chem. Soc. 2004, 126, 1646.
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101
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0037420381
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The transient absorption bands in the NIR region agree with the absorption bands due to TCNQ""; see
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The transient absorption bands in the NIR region agree with the absorption bands due to TCNQ""; see: V. Ganesan, S.V. Rosokha, J. K. Kochi, J. Am. Chem. Soc. 2003, 125, 2559.
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70349129853
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No direct electron transfer from singlet-excited H2P to TCNQ occurs under the present experimental conditions with small concentrations of TCNQ.
-
No direct electron transfer from singlet-excited H2P to TCNQ occurs under the present experimental conditions with small concentrations of TCNQ.
-
-
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103
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0035818097
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I. W. Chiang, B. E. Brinson, A. Y.Huang, P.A. Willis, M. J. Bronikowski, J. L Margrave, R. E. Smalley, R. H. Hauge, J. Phys. Chem. B 2001, 105, 8297.
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104
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84903931679
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Butterworth-Heinemann, Burlington
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W. L. F. Armarego, C. L. L. Chai, Purification of Laboratory Chemicals, 5th ed., Butterworth-Heinemann, Burlington, 2003.
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Armarego, W.L.F.1
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70349152087
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b)L.R. Melby, R.J. Harder, W. R. Hertler, W. Mahler, R. E. Benson, W. E. Mochel, J. Am. Chem. Soc. 1962, 84, 331 A;
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c) O. W. Webster, W Mahler, R. E. Benson, J. Am. Chem. Soc. 1962, 84, 3678.
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25444491766
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The ET reduction of cup-shaped nanocarbon causes them to disperse in a polar organic solvent (such as THF or DMF), leading to covalently functionalization of functional groups through radical addition. Reduced carbon nanotubes were also arylated by the reaction with 4-iodoaniline, see: a
-
The ET reduction of cup-shaped nanocarbon causes them to disperse in a polar organic solvent (such as THF or DMF), leading to covalently functionalization of functional groups through radical addition. Reduced carbon nanotubes were also arylated by the reaction with 4-iodoaniline, see: a) J. Chattopadhyay, A. K. Sadana, F. Liang, J. M. Beach, Y.Xiao, R. H. Hauge, W. E. Billups, Org. Lett. 2005, 7, 4067;
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b) J. J. Stephenson, A. K. Sadana, A. L. Higginbotham, J. M. Tour, Chem. Mater. 2006, 18, 4658.
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Stephenson, J.J.1
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110
-
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70349113391
-
-
The other substituted TCPP (di- and tetra-substituted TCPP) is also formed as a by-product. After the reaction, tetra-substituted TCPP and trace of di-substituted TCPP were detected by MALDI-TOF mass spectroscopy. These by-products can be easily removed by silica gel column chromatography. The characterization of tri-substituted TCPP also has been carried out by MALDI-TOF mass spectroscopy after the purification. See the Supporting Information (Figure Sl).
-
The other substituted TCPP (di- and tetra-substituted TCPP) is also formed as a by-product. After the reaction, tetra-substituted TCPP and trace of di-substituted TCPP were detected by MALDI-TOF mass spectroscopy. These by-products can be easily removed by silica gel column chromatography. The characterization of tri-substituted TCPP also has been carried out by MALDI-TOF mass spectroscopy after the purification. See the Supporting Information (Figure Sl).
-
-
-
-
111
-
-
70349093432
-
-
n solution.
-
n solution.
-
-
-
-
112
-
-
0142104260
-
-
For synthesis of tetrakis(Ar-octadecyl-4-aminocarbonylphenyl)porphyrin, see a
-
For synthesis of tetrakis(Ar-octadecyl-4-aminocarbonylphenyl)porphyrin, see a) S. N. Gradl, J. P.Felix, E. Y.Isacoff, M. L. Garcia, D. Trauner, J. Am. Chem. Soc. 2003, 125, 12668.
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Gradl, S.N.1
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Trauner, D.5
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113
-
-
70349102413
-
-
2P) as the reference compound was prepared as follows: A solution containing tetrakis(4-carboxyphenyl) porphine (50 mg, 63 umol), thionyl chloride (0.20 mL, 2.74 mmol), and pyridine (0.20 mL) in benzene (15.0 mL) was stirred for 2 h under nitrogen atmosphere. The excess pyridine and benzene were removed under reduced pressure. The residue was redissolved in a mixture containing octadecylamine (70.0 mg, 260 umol), pyridine (0.1 mL), and DMF (10.0 mL). The solution was stirred at room temperature for 24 h. The excess amount of pyridine and DMF were removed under reduced pressure. The crude samples were further purified by reprecipitation from chloroform-acetonitrile to obtain tetrakis(Ar-octadecyl-4-aminocarbonylphenyl) porphyrin.
-
2P) as the reference compound was prepared as follows: A solution containing tetrakis(4-carboxyphenyl) porphine (50 mg, 63 umol), thionyl chloride (0.20 mL, 2.74 mmol), and pyridine (0.20 mL) in benzene (15.0 mL) was stirred for 2 h under nitrogen atmosphere. The excess pyridine and benzene were removed under reduced pressure. The residue was redissolved in a mixture containing octadecylamine (70.0 mg, 260 umol), pyridine (0.1 mL), and DMF (10.0 mL). The solution was stirred at room temperature for 24 h. The excess amount of pyridine and DMF were removed under reduced pressure. The crude samples were further purified by reprecipitation from chloroform-acetonitrile to obtain tetrakis(Ar-octadecyl-4-aminocarbonylphenyl) porphyrin.
-
-
-
|