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Volumn 27, Issue 19, 2008, Pages 5130-5138

Synthesis, properties, and structure of tethered molybdenum alkylidenes

Author keywords

[No Author keywords available]

Indexed keywords

AGOSTIC INTERACTIONS; ALKOXIDE; ALKYLIDENE; ALKYLIDENES; ANCILLARY LIGANDS; DIISOPROPYLBENZENE; NEW CLASSES; NMR SPECTROSCOPIES; QUINUCLIDINE; SOLIDSTATE STRUCTURES; TETHERED SYSTEMS; TRIFLATE; X-RAY DIFFRACTIONS;

EID: 54249107161     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om800650v     Document Type: Article
Times cited : (13)

References (90)
  • 1
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    • Grubbs, R. H, Ed, Wiley-VCH: Chichester, U.K
    • (a) Grubbs, R. H., Ed. Handbook of Metathesis; Wiley-VCH: Chichester, U.K., 2003.
    • (2003) Handbook of Metathesis
  • 6
    • 0032560969 scopus 로고    scopus 로고
    • For applications in asymmetric olefin metathesis: (a) La, D. S.; Alexander, J. B.; Cefalo, D. R.; Graf, D. D.; Hoveyda, A. H.; Schrock, R. R. J. Am. Chem. Soc. 1998, 120, 9720.
    • For applications in asymmetric olefin metathesis: (a) La, D. S.; Alexander, J. B.; Cefalo, D. R.; Graf, D. D.; Hoveyda, A. H.; Schrock, R. R. J. Am. Chem. Soc. 1998, 120, 9720.
  • 20
    • 22744448499 scopus 로고    scopus 로고
    • For some selected applications to organic synthesis: o
    • For some selected applications to organic synthesis: (o) Nicolaou, K. C.; Bulger, P. G.; Sarlah, D. Angew. Chem., Int. Ed. 2005, 44, 4490.
    • (2005) Angew. Chem., Int. Ed , vol.44 , pp. 4490
    • Nicolaou, K.C.1    Bulger, P.G.2    Sarlah, D.3
  • 23
    • 0037137314 scopus 로고    scopus 로고
    • For application of olefin metathesis in the synthesis of specialized materials: r
    • For application of olefin metathesis in the synthesis of specialized materials: (r) Anders, U.; Nuyken, O.; Buchmeiser, M. R.; Wurst, K. Macromolecules 2002, 35, 9029.
    • (2002) Macromolecules , vol.35 , pp. 9029
    • Anders, U.1    Nuyken, O.2    Buchmeiser, M.R.3    Wurst, K.4
  • 51
    • 11544274511 scopus 로고    scopus 로고
    • For replacement of Inflate with alkoxide: (a) Schrock, R. R. Polyhedron 1995, 14, 3177. Recently, other replacements have been found to be highly reactive as well. For replacement of triflate to alkyl alkoxide:
    • For replacement of Inflate with alkoxide: (a) Schrock, R. R. Polyhedron 1995, 14, 3177. Recently, other replacements have been found to be highly reactive as well. For replacement of triflate to alkyl alkoxide:
  • 72
    • 0000439604 scopus 로고
    • For a different approach to a similar complex using aryl isocyanates, see for example: b
    • For a different approach to a similar complex using aryl isocyanates, see for example: (b) Bryson, N.; Youinou, M.-T.; Osborn, J. A. Organometallics 1991, 10, 3389.
    • (1991) Organometallics , vol.10 , pp. 3389
    • Bryson, N.1    Youinou, M.-T.2    Osborn, J.A.3
  • 77
    • 54249167224 scopus 로고    scopus 로고
    • The τ value is calculated using the equation t = (α-β)/60, where a and β are the largest and next to largest angles around the metal center. For an ideal square pyramid τ = 0, and τ = 1 for an ideal trigonal bipyramid: (a) Alvarez, S.; Llunell, M. Dalton Trans. 2000, 3288.
    • The τ value is calculated using the equation t = (α-β)/60, where a and β are the largest and next to largest angles around the metal center. For an ideal square pyramid τ = 0, and τ = 1 for an ideal trigonal bipyramid: (a) Alvarez, S.; Llunell, M. Dalton Trans. 2000, 3288.
  • 82
    • 34547363930 scopus 로고    scopus 로고
    • For examples of five-coordinate alkylidene JCH couplings see ref 12. For general references on agostic interactions, see: Brookhart, M, Green, M. L. H, Parkin, G. Proc. Natl. Acad. Sci. 2007, 104, 6908
    • CH couplings see ref 12. For general references on agostic interactions, see: Brookhart, M.; Green, M. L. H.; Parkin, G. Proc. Natl. Acad. Sci. 2007, 104, 6908.
  • 84
    • 54249091784 scopus 로고    scopus 로고
    • Manuscript in preparation
    • Lokare, K. S.; Odom, A. L. Manuscript in preparation.
    • Lokare, K.S.1    Odom, A.L.2
  • 90
    • 0031842252 scopus 로고    scopus 로고
    • The literature procedure led to an out-of-control exothermic reaction when attempted. The procedure was modified for a more controlled reaction: Ghiaci, M.; Asghari, J. Synth. Commun. 1998, 28, 2213.
    • The literature procedure led to an out-of-control exothermic reaction when attempted. The procedure was modified for a more controlled reaction: Ghiaci, M.; Asghari, J. Synth. Commun. 1998, 28, 2213.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.