Synthesis of A,B-alternating copolymers by ring-opening-insertion-metathesis polymerization

Angewandte Chemie - International Edition

Volumn 41, Issue 20, 2002, Pages 3839-3841

  Choi, Tae Lim ^a   Rutenberg, Isaac M ^a   Grubbs, Robert H ^a  

^a California Institute of Technology   (United States)

Author keywords

Copolymerization; Cross coupling; Metathesis; Ring opening polymerization; Ruthenium

Indexed keywords

CHEMICAL BONDS; MONOMERS; OLEFINS; POLYMERIZATION; SYNTHESIS (CHEMICAL);

SELECTIVITY;

COPOLYMERS;

COPOLYMER; ACRYLIC ACID DERIVATIVE; CYCLOALKANE DERIVATIVE; POLYMER; RUTHENIUM;

ARTICLE; POLYMERIZATION; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; RING OPENING METATHESIS POLYMERIZATION; SYNTHESIS; CATALYSIS; CHEMISTRY; MOLECULAR WEIGHT;

ACRYLATES; CATALYSIS; CYCLOPARAFFINS; MOLECULAR WEIGHT; POLYMERS; RUTHENIUM;

EID: 0037131461     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3773(20021018)41:20<3839::AID-ANIE3839>3.0.CO;2-H     Document Type: Article

References (24)

1. a) G. Odian, Principles of Polymerizations, Wiley, New York, 1991:
2. b) E. Drent, P. H. M. Budzelaar, Chem. Rev. 1996, 96, 663.
3. a) K. J. Ivin, J. C. Mol, Olefin Metathesis and Metathesis Polymerization, Academic Press, San Diego, 1997;
4. b) R. H. Grubbs, E. Khosravi, Mater. Sci. Technol. 1999, 20, 65;
5. c) M. R. Buchmeiser, Chem. Rev. 2000, 100, 1565.
6. For a recent report using catalyst 3, see: S. E. Lehman, K. B. Wagener, Macromolecules 2002, 35, 48, and references therein.
7. a) B. A. Samak, A. G. Carvill, J. G. Hamilton, J. J. Rooney, J. M. Thompson, Chem. Commun. 1997, 2057;
8. b) B. A. Samak, V. AmirEbrahimi, D. G. Corry, J. G. Hamilton, S. Rigby, J. J. Rooney, J. M. Thompson, J. Mol. Catal. 2000, 160, 13;
9. c) M. F. Ilker, E. B. Coughlin, Macromolecules 2002, 35, 54.
10. R. R. Schrock, Acc. Chem. Res. 1990, 23, 158.
11. P. Schwab, R. H. Grubbs, J. W. Ziller, J. Am. Chem. Soc. 1996, 118, 100.
12. M. Scholl, S. Ding, C. W. Lee, R. H. Grubbs, Org. Lett. 1999, 1, 953.
13. a) A. K. Chatterjee, R. H. Grubbs, Org. Lett. 1999, 1, 1751;
14. b) A. K. Chatterjee, J. P. Morgan, M. Scholl, R. H. Grubbs, J. Am. Chem. Soc. 2000, 122, 3783;
15. c) T.-L. Choi, A. K. Chatterjee, R. H. Grubbs, Angew. Chem. 2001, 113, 1317; Angew. Chem. Int. Ed. 2001, 40, 1277;
16. c) T.-L. Choi, A. K. Chatterjee, R. H. Grubbs, Angew. Chem. 2001, 113, 1317; Angew. Chem. Int. Ed. 2001, 40, 1277;
17. d) A. K. Chatterjee, T.-L. Choi, R. H. Grubbs, Synlett 2001, 1034;
18. e) T.-L. Choi, R. H. Grubbs, Chem. Commun. 2001, 2648;
19. f) C. W. Lee, T.-L. Choi, R. H. Grubbs, J. Am. Chem. Soc. 2002, 124, 3224.
20. C. W. Bielawski, R. H. Grubbs, Angew. Chem. 2000, 112, 3025; Angew. Chem. Int. Ed. 2000, 39, 2903.
21. C. W. Bielawski, R. H. Grubbs, Angew. Chem. 2000, 112, 3025; Angew. Chem. Int. Ed. 2000, 39, 2903.
22. R. R. Schrock, K. B. Yap, D. C. Yang, H. Sitzmann, L. R. Sita, G. C. Bazan, Macromolecules 1989, 22, 3191.
23. The number was obtained by AM1 calculation from Spartan v. 1.1, Wavefunction.
24. T.-L. Choi, C. W. Lee, A. K. Chatterjee, R. H. Grubbs, J. Am. Chem. Soc. 2001, 123, 10417,