Hyperbranched macromolecules via olefin metathesis

Journal of the American Chemical Society

Volumn 129, Issue 42, 2007, Pages 12672-12673

  Gorodetskaya, Irina A ^a   Choi, Tae Lim ^a,b   Grubbs, Robert H ^a  

^a California Institute of Technology   (United States)

^b Cheil Industries Inc   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

ACRYLIC ACID; ALKENE; DENDRIMER; MONOMER; POLYMER;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; MACROMOLECULE; MOLECULAR WEIGHT; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYMERIZATION; REACTION ANALYSIS; RING CLOSING METATHESIS; SOLUBILITY;

EID: 35549012411     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0759040     Document Type: Article

References (23)

1. For recent reviews on hyperbranched polymers, see: Kim, Y. H. J. Polym. Sci., Part A: Polym. Chem. 1998, 36, 1685.
2. Voit, B. J. Polym. Sci. Part A: Polym. Chem. 2000, 38, 2505.
3. Voit, B. J. Polym. Sci., Part A: Polym. Chem. 2005, 43, 2679.
4. Newkome, G. R.; Moorefiled, C. N.; Vögtle, F. Dendrimers and Dendrons: Concepts, Synthesis, Applications; VCH: Weinheim, Germany, 2001.
5. For recent reviews on dendrimers, see: Bosman, A. W.; Janssen, H. M; Meijer, E. W. Chem. Rev. 1999, 99, 1665.
6. Grayson, S. M.; Fréchet, J. M. J. Chem. Rev. 2001, 101, 3819.
7. Stiriba, S.-E.; Frey, H.; Haag, R. Angew. Chem., Int. Ed. 2002, 41, 1329.
8. Piotti, M. E.; Rivera, F.; Bond, R.; Hawker, C. J.; Fréchet, J. M. J. J. Am. Chem. Soc. 1999, 121, 9471.
9. Astruc, D.; Chardac, F. Chem. Rev. 2001, 101, 2991.
10. Zeng, F.; Zimmerman, S. C. Chem. Rev. 1997, 97, 1681.
11. Gibson, H. W.; Yamaguchi, N.; Hamilton, L.; Jones, J. W. J. Am. Chem. Soc. 2002, 124, 4653.
12. Hobson, L. J.; Feast, W. J. Chem. Commun. 1997, 2067.
13. Fréchet, J. M. J.; Hawker, C. J.; Gitsov, I.; Leon, J. W. J. Macromol. Sci., Pure Appl. Chem. 1996, A33, 1399.
14. For reviews on ADMET, see: Lehman, E.; Wagener, K. B. ADMET Polymerization. In Handbook of Metathesis; Grubbs, R. H., Ed.; Wiley-VCH: Weinheim, Germany, 2003; Vol. 3, pp 283-353.
15. Schwendeman, J. E.; Church, C. A.; Wagener, K. B. Adv. Synth. Catal. 2002, 344, 597.
16. Chatterjee, A. K.; Choi, T.-L.; Sanders, D. P.; Grubbs, R. H. J. Am. Chem. Soc. 2003, 125, 11360.
17. In fact, a similar concept has been previously demonstrated in the synthesis of alternating copolymers, see: (a) Choi, T.-L.; Rutenberg, I. M.; Grubbs, R. H. Angew. Chem., Int. Ed. 2002, 41, 3839.
18. (b) Demel, S.; Slugovc, C.; Stelzer, F.; Fodor-Csorba, K.; Galli, G. Macromol. Rapid Commun. 2003, 24, 636.
19. Konzelman, J.; Wagener, K. B. Macromolecules 1995, 28, 4686.
20. Please see Supporting Information for a more detailed explantation of the NMR spectral analysis.
21. Odian, G. Principles of Polymerization, Fourth Edition; Wiley: Hoboken, 2004; pp 114-117.
22. Radke, W.; Müller, A. H. E. Macromolecules 2005, 38, 3949.
23. Sperling, L. H. Introduction to Physical Polymer Science, 2nd ed.; Wiley: New York, 1992; Chapter 3, 104-105.