Reactions of Mo(NAr)(CH-t-Bu)(CH 2-t-Bu) 2 with Alcohols to Give Metathesis Catalysts of the Type Mo(NAr) (CH-t-Bu) (CH 2-t-Bu) (OR)

Organometallics

Volumn 23, Issue 8, 2004, Pages 1643-1645

  Sinha, Amritanshu ^a   Schrock, Richard R ^a  

^a MASSACHUSETTS INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ASYMMETRIC CATALYSTS; ASYMMETRIC METATHESIS; ENANTIOMERS; METATHESIS CONVERSION;

ALCOHOLS; APPROXIMATION THEORY; CATALYSTS; CHEMICAL BONDS; COMPETITION; COMPLEXATION; DECOMPOSITION; MOLYBDENUM COMPOUNDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXIDATION; PROTONS; SILICA;

REACTION KINETICS;

EID: 2342428502     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om030639m     Document Type: Article

References (13)

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2. Ehrenfeld, D.; Kress, J.; Moore, B. D.; Osborn, J. A.; Schoettel, G. J. Chem. Soc., Chem. Commun. 1987, 129.
3. Schrook, R. R.; Murdzek, J. S.; Bazan, G. C.; Robbins, J.; DiMare, M.; O'Regan, M. J. Am. Chem. Soc. 1990, 112, 3875.
4. Feldman, J.; Schrock, R. R. Prog. Inorg. Chem. 1991, 39, 1.
5. Schrock, R. R. Chem. Rev. 2002, 102, 145.
6. Schrock, R. R.; DePue, R. T.; Feldman, J.; Yap, K. B.; Yang, D. C.; Davis, W. M.; Park, L. Y.; DiMare, M.; Schofield, M.; Anhaus, J.; Walborsky, E.; Evitt, E.; Krüger, C.; Betz, P. Organometallics 1990, 9, 2262.
7. 5) has been confirmed in an X-ray study, details of which will be provided in a future paper.
8. Schrock, R. R. In Reactions of Coordinated Ligands; Braterman, P. R., Ed.; Plenum: New York, 1986.
9. Edwards, D. S.; Biondi, L. V.; Ziller, J. W.; Churchill, M. R.; Schrock, R. R. Organometallics 1983, 2, 1505.
10. Chabanas, M.; Baudouin, A.; Copéret, C.; Basset, J.-M.; Lukens, W.; Lesage, A.; Hediger, S.; Emsley, L. J. Am. Chem. Soc. 2003, 125, 492.
11. Copéret, C.; Chabanas, M.; Saint-Arroman, R. P.; Basset, J.-M. Angew. Chem., Int. Ed. 2003, 42, 156.
12. LaPointe, A. M.; Schrock, R. R. Organometallics 1995, 14, 1875.
13. An example of R*OH is monomethyl-protected (R)-binaphthol. Similar results have been obtained by M. Duval-Lungulescu with a variety of chiral alcohols