Ring-Opening of a Cyclic Imine: The First Step of Imine ROMP

Organometallics

Volumn 18, Issue 21, 1999, Pages 4250-4252

  Cantrell, Gidget K ^a   Geib, Steven J ^a   Meyer, Tara Y ^a  

^a UNIVERSITY OF PITTSBURGH   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000780539     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om990522r     Document Type: Article

References (22)

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11. ch = 139 Hz), 174.02,152.29, 147.99, 143.67, 127.46, 127.16(q), 124.86(q), 80.32(q), 77.45(q), 65.33, 43.97,35.41, 31.64, 29.99, 29.50, 25.35, 24.71, 24.25, 24.50, 23.92, 23.30, 22.95, 21.27.
12. 3; Z = 8; R(F) = 0.1237, R(wF) = 0.2090 (all data); GOF = 1.195.
13. Nugent, W. A. Metal-Ligand Multiple Bonds-, John Wiley & Sons: New York, 1988.
14. Schrock, R. R.; Luo, S.; Lee, J. C., Jr.; Zanetti, N. C.; Davis, W. M. J. A. Chem. Soc. 1996, 118, 3883-3895.
15. a) Kress, J.; Osborn, J. A. Angew, Chem., Int. Ed. Engl. 1902, 31,1585-1587.
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17. 6 at 25° C): δ 154.17, 143.05, 127.40 (q), 126.54, 123.86, 123.42, 123.22, 80.27(q), 67.87, 33.26, 32.98, 30.40, 30.17, 29.0, 25.30, 24.99, 24.00.
18. 3).
19. Jolly, M.; Mitchell, J. P.; Gibson, V. C. J. Chem. Soc., Dalton Trans. 1992, 1331-1332.
20. (a) Schrock, R. R; DePue, R. T.; Feldman, J.; Schaverien, C. J.; Dewan, J. C.; Liu, A. H. J. Am. Chem. Soc. 1988, 110, 1423-1435.
21. (b) Bazan, G, C.; Khosravi, E.; Schrock, R. R.; Feast, W. J.; Gibson, V. C.; O'Regan, M. B.; Thomas, J. K.; Davis, W. M. J. Am. Chem. Soc. 1990, 112, 8378-8387.
22. The "rearrangement" may involve dissociation and recoordination.