Mechanistic studies on the catalytic asymmetric mannich-type reaction with dihydroisoquinolines and development of oxidative mannich-type reactions starting from tetrahydroisoquinolines

Journal of Organic Chemistry

Volumn 73, Issue 15, 2008, Pages 5859-5871

  Dubs, Christian ^a   Hamashima, Yoshitaka ^a   Sasamoto, Naoki ^a   Seidel, Thomas M ^a   Suzuki, Shoko ^a   Hashizume, Daisuke ^a   Sodeoka, Mikiko ^a  

^a RIKEN   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ADDITION REACTIONS; CHEMICAL REACTIONS; MECHANICS; PALLADIUM;

ASYMMETRIC ADDITION; CHEMICAL EQUATIONS; DIHYDROISOQUINOLINES; IN-SITU; MALONATES; MANNICH TYPE REACTIONS; MECHANISTIC STUDIES; TETRAHYDROISOQUINOLINES;

PALLADIUM COMPOUNDS;

ACETAL DERIVATIVE; ACID; BASE; IMINE; ISOQUINOLINE DERIVATIVE; MALONIC ACID DERIVATIVE; OXIDIZING AGENT; PALLADIUM COMPLEX; QUINOLIZIDINE DERIVATIVE; TETRAHYDROISOQUINOLINE;

ADDITION REACTION; ARTICLE; ASYMMETRIC CATALYSIS; CARBON NUCLEAR MAGNETIC RESONANCE; CATALYST; CHIRALITY; COMPLEX FORMATION; ENANTIOSELECTIVITY; INFRARED SPECTROSCOPY; MANNICH REACTION; OXIDATION; PROTON NUCLEAR MAGNETIC RESONANCE; QUANTUM YIELD; REACTION ANALYSIS;

AMINES; CATALYSIS; CRYSTALLOGRAPHY, X-RAY; ESTERS; IMINES; ISOQUINOLINES; LIGANDS; MAGNETIC RESONANCE SPECTROSCOPY; MANNICH BASES; MODELS, MOLECULAR; MOLECULAR STRUCTURE; OXIDATION-REDUCTION; PALLADIUM; SPECTROPHOTOMETRY, INFRARED; STEREOISOMERISM; TEMPERATURE;

EID: 48249118329     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo800800y     Document Type: Article

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