Asymmetric Intramolecular Allylic Amination: Straightforward Approach to Chiral C1-Substituted Tetrahydroisoquinolines

Synlett

Volumn , Issue 12, 2003, Pages 1809-1812

  Ito, Katsuji ^a   Akashi, Suemi ^a   Saito, Bunnai ^b   Katsuki, Tsutomu ^b  

^a FUKUOKA UNIVERSITY OF EDUCATION   (Japan)

^b KYUSHU UNIVERSITY   (Japan)

Author keywords

Asymmetric allylic amination; Asymmetric catalysis; Chiral P N ligand; Palladium; Tetrahydroisoquinoline

Indexed keywords

ALLYL COMPOUND; CARNEGINE; PALLADIUM; TETRAHYDROISOQUINOLINE DERIVATIVE;

AMINATION; ARTICLE; CATALYSIS; CHIRALITY; ENANTIOSELECTIVITY; MOLECULAR DYNAMICS; SYNTHESIS;

EID: 0142123967     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2003-41502     Document Type: Article

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53. A larger scale cyclization of 1b (0.64 mmol scale) afforded 6 with slightly reduced enantioselectivity (85% ee). This compound 6 was used for the following reactions.
54. 3d