Catalytic enantioselective Michael reaction of 1,3-dicarbonyl compounds via formation of chiral palladium enolate

Advanced Synthesis and Catalysis

Volumn 347, Issue 11-13, 2005, Pages 1576-1586

  Hamashima, Yoshitaka ^a   Hotta, Daido ^a   Umebayashi, Natsuko ^a   Tsuchiya, Yasunori ^a   Suzuki, Takeyuki ^b   Sodeoka, Mikiko ^a,c  

^a TOHOKU UNIVERSITY   (Japan)

^b TOHOKU PHARMACEUTICAL UNIVERSITY   (Japan)

^c INST OF PHYS AND CHEMICAL RESEARCH   (Japan)

Author keywords

, unsaturated compounds; 1,3 dicarbonyl compounds; Asymmetric catalysis; Michael reaction; Palladium enolates

Indexed keywords

EID: 27544474635     PISSN: 16154150     EISSN: None     Source Type: Journal    
DOI: 10.1002/adsc.200505199     Document Type: Article

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105. [24]
106. [6g]
107. [11i,j,o]
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110. [24]
111. TfOH itself was reported to promote the Michael reaction to give a racemic product, see: H. Kotsuki, K. Arimura, T. Ohishi, R. Maruzasa, J. Org. Chem. 1999, 64, 3770-3773;
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113. The space-filling model depicted in Figure 2 was generated by MM3 calculation using CAche 5.0.