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41749100479
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To avoid confusion in the nomenclature of the polymers obtained from the ITC of the racemic hydroxy-esters and to remain consistent with our previously described polymers (see ref. 11, we decided to take the corresponding lactone as the monomer unit. Therefore the polymers corresponding to Me-6HH, Me-7HO, Me-8HN and Me-13HT are respectively poly(6-methyl-ε-caprolactone, poly(6MeCL, poly(7-methylheptanolactone, poly(7-MeHL, poly(8- methyloctanolactone, poly(8-MeOL, and poly(13-methyltridecanolactone, poly13-MeTL
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To avoid confusion in the nomenclature of the polymers obtained from the ITC of the racemic hydroxy-esters and to remain consistent with our previously described polymers (see ref. 11), we decided to take the corresponding lactone as the monomer unit. Therefore the polymers corresponding to Me-6HH, Me-7HO, Me-8HN and Me-13HT are respectively poly(6-methyl-ε-caprolactone) (poly(6MeCL)), poly(7-methylheptanolactone) (poly(7-MeHL)), poly(8- methyloctanolactone) (poly(8-MeOL)) and poly(13-methyltridecanolactone) (poly(13-MeTL)).
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34
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84993914562
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for Me-6HH, Me-7HO, and Me-8HN; The monomers described in the study have been prepared previously via other synthetic approaches: See a
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The monomers described in the study have been prepared previously via other synthetic approaches: See (a) Fouque, E.; Rousseau, G. Synthesis 1989, 661-666 for Me-6HH, Me-7HO, and Me-8HN;
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Synthesis
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Fouque, E.1
Rousseau, G.2
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36
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0348048814
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Hasdemir, B.; Yusufoǧlu, A. Tetrahedron Asym 2004, 15, 65-68 for Me-13HT. The analytical data presented here are consistent with previously published data.
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(c) Hasdemir, B.; Yusufoǧlu, A. Tetrahedron Asym 2004, 15, 65-68 for Me-13HT. The analytical data presented here are consistent with previously published data.
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0001501091
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(a) Jung, H. M.; Koh, J. H.; Kim, M.-J.; Park, J. Org Lett 2000, 2, 409-411;
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41749093289
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Carother's formula: degree of polymerization, 1/1 -conversion
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Carother's formula: degree of polymerization = 1/(1 -conversion).
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40
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41749108504
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Since the rate of the reaction is determined by the racemization catalyst, increasing the amount of Novozym 435 does not lead to a faster reaction.
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Since the rate of the reaction is determined by the racemization catalyst, increasing the amount of Novozym 435 does not lead to a faster reaction.
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41
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34547377175
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Marr, A. C.; Pollock, C.; Saunders, G. C. Organometallics 2007, 26, 3283-3285.
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Marr, A.C.1
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Saunders, G.C.3
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42
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41749101625
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The use of racemization catalysts that do require the addition of a base lead consistently to deactivation of Novozym 435 in ITC reactions. The exact reason for this deactivation is currently unclear
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The use of racemization catalysts that do require the addition of a base lead consistently to deactivation of Novozym 435 in ITC reactions. The exact reason for this deactivation is currently unclear.
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