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Volumn 36, Issue 11, 1997, Pages 1211-1212

Enzymatic Resolution of Alcohols Coupled with Ruthenium-Catalyzed Racemization of the Substrate Alcohol

Author keywords

Alcohols; Asymmetric catalysis; Chiral resolution; Enzyme catalysis; Ruthenium

Indexed keywords


EID: 0030789621     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199712111     Document Type: Article
Times cited : (315)

References (42)
  • 7
    • 0001251438 scopus 로고
    • b) C.-S. Chen, C. J. Sih, Angew. Chem. 1989, 101, 711; Angew. Chem. Int. Ed. Engl. 1989, 28, 695.
    • (1989) Angew. Chem. , vol.101 , pp. 711
    • Chen, C.-S.1    Sih, C.J.2
  • 8
    • 84990106353 scopus 로고
    • b) C.-S. Chen, C. J. Sih, Angew. Chem. 1989, 101, 711; Angew. Chem. Int. Ed. Engl. 1989, 28, 695.
    • (1989) Angew. Chem. Int. Ed. Engl. , vol.28 , pp. 695
  • 25
    • 0642379512 scopus 로고    scopus 로고
    • unpublished results
    • a) R. L. Chowdhury, unpublished results;
    • Chowdhury, R.L.1
  • 28
    • 0001340263 scopus 로고
    • Correction: ibid. 1992, 57, 6082
    • a) H. E. Schink, J. E. Bäckvall, J. Org. Chem. 1992, 57, 1588. Correction: ibid. 1992, 57, 6082.
    • (1992) J. Org. Chem. , vol.57 , pp. 1588
    • Schink, H.E.1    Bäckvall, J.E.2
  • 32
    • 0642318122 scopus 로고    scopus 로고
    • note
    • Starting from (±)-cis-2-methylcyclohexanol a cis/trans ratio of 46:54 was obtained in 14 h at 80°C with 2 mol% of 1, 10 mol% NaOH, and 1 equiv of 2-methylcyclohexanone in 2 mL of tBuOH.
  • 42
    • 0642318117 scopus 로고    scopus 로고
    • note
    • In this process the acetaldehyde is reduced to ethanol, which is rapidly acylated, and the process becomes irreversible.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.