Switching from S- to R-selectivity in the Candida antarctica lipase B-catalyzed ring-opening of ω-methylated lactones: Tuning polymerizations by ring size

Journal of the American Chemical Society

Volumn 129, Issue 23, 2007, Pages 7393-7398

  Van Buijtenen, Jeroen ^a   Van As, Bart A C ^a   Verbruggen, Marloes ^a   Roumen, Luc ^a   Vekemans, Jef A J M ^a   Pieterse, Koen ^a   Hilbers, Peter A J ^a   Hulshof, Lumbertus A ^a   Palmans, Anja R A ^a   Meijer, E W ^a  

^a EINDHOVEN UNIVERSITY OF TECHNOLOGY   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

METHYLATED LACTONES; RING-OPENING; S-SELECTIVITY;

CATALYSIS; ENANTIOSELECTIVITY; LIPASES; POLYESTERS; POLYMERIZATION; REACTION RATES;

ESTERS;

ESTER; FUNGAL ENZYME; LACTONE DERIVATIVE; LIPASE B; OMEGA METHYLATED LACTONE; UNCLASSIFIED DRUG;

ARTICLE; CANDIDA ANTARCTICA; CATALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; CONFORMATIONAL TRANSITION; ENANTIOSELECTIVITY; MOLECULAR MODEL; POLYMERIZATION; RING OPENING; TRANSESTERIFICATION;

BINDING SITES; CATALYSIS; COMPUTER SIMULATION; FUNGAL PROTEINS; LACTONES; LIPASE; METHYLATION; MODELS, MOLECULAR; MOLECULAR CONFORMATION; POLYMERS; STEREOISOMERISM;

EID: 34250876404     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja071241a     Document Type: Article

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