Quantitative Analyses of Biochemical Kinetic Resolutions of Enantiomers

Journal of the American Chemical Society

Volumn 104, Issue 25, 1982, Pages 7294-7299

  Chen, Ching Shih ^a   Fujimoto, Yoshinori ^a   Girdaukas, Gary ^a   Sih, Charles J ^a  

^a UNIVERSITY OF WISCONSIN MADISON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 20644469267     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00389a064     Document Type: Article

References (18)

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2. For examples of biochemical kinetic resolution, see: Bentley, R. In “Molecular Asymmetry in Biology”; Academic Press: New York, 1969; Vol. 1, Chapter 6.
3. Jones, J. B.; Beck, J. F. In “Techniques in Chemistry”; Jones, J. B., Sih, C. J., Perlman, D., Eds.; Wiley: New York, 1976; Vol. 10, Chapter 4.
4. For a definition of V/K, see: Fersht, A. In “Enzyme Structure and Mechanism”; Freeman: San Francisco, 1977; Chapters 3 and 10.
5. Walsh, C. In “Enzymatic Reaction Mechanisms”; Freeman: San Francisco, 1979; p 120.
6. Meister, A.; Levintow, L.; Kingsley, R. B.; Greenstein, J. P. J. Biol. Chem. 1951, 192, 535.
7. A comprehensive treatment of V/K effects with competitive substrates is beyond the scope of this paper. For a lucid explanation, see: Northrop, D. J. Am. Chem. Soc. 1981, 103, 1208.
8. Greenstein, J. P.; Winitz, M. In “Chemistry of the Amino Acids”; Wiley: New York, 1961; Vol. 2, p 1734.
9. Krisch, K. In “The Enzymes”, 3rd ed.; Academic Press: New York, 1971; Vol. 5, Chapter 3.
10. E). Implicit functions (eq 5 and 6) were solved by parametric representations. See: Buck, R. C. In “Advanced Calculus”, 2nd ed.; McGraw Hill: New York, 1965; p 313. Copies of the computer programs are available upon request.
11. Jones, J. B.; Marr, P. W. Tetrahedron Lett. 1973, 3165.
12. Chen, C. S.; Fujimoto, Y.; Sih, C. J. J. Am. Chem. Soc. 1981, 103, 3580.
13. Meyers, A. I.; Yamamoto, Y. J. Am. Chem. Soc. 1981, 103, 4278.
14. Irwin, A. J.; Jones, J. B. J. Am. Chem. Soc. 1977, 99, 556.
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17. Masamune, S.; Choy, W.; Kerdesky, F. A. J.; Imperiali, B. J. Am. Chem. Soc. 1981, 103, 1566.
18. Evans, D. A.; Bartroli, J.; Shih, T. L. J. Am. Chem. Soc. 1981, 103, 2127.