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14
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15
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32744464469
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note
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The generation of the oligomer equals the number of enzymatic ring-opening reactions performed in its synthesis. The term generation was inspired by dendrimer nomenclature.
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16
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20644469267
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The E ratio of the ring-opening of 6-MeCL by Novozym 435 was determined to be 12 at 45 °C. The E ratio was calculated according to Chen et al. J. Am. Chem. Soc. 1982, 104, 7294.
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Chen1
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17
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0002974735
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Hara, Y.; Inagaki, H.; Nishimura, S.; Wada, K. Chem. Lett. 1992, 1983.
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Hara, Y.1
Inagaki, H.2
Nishimura, S.3
Wada, K.4
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18
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32744463352
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note
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2OH signal at δ = 4.0 ppm.
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19
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32744475780
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note
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1H NMR for the intrachain esters and the end-groups, and ee is the measured enantiomeric excess of the methyl ester.
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