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CuCl is well suited to force this transformation to completion through a dissociative mechanism by trapping the phosphane ligand and creating an intermediate 14-electron complex.[13,14
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Note added in proof: Recently, another interesting method for the removal of ruthenium from metathesis reactions by using a polar isocyanide was reported; see
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Note added in proof: Recently, another interesting method for the removal of ruthenium from metathesis reactions by using a polar isocyanide was reported; see: B. R. Galan, K. P. Kalbarczyk, S. Szczepankiewicz, J. B. Keister, S. T. Diver, Org. Lett. 2007, 9, 1203-1206.
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2, removal of ruthenium by-products from olefin metathesis products is possible by simple aqueous extraction; see: S. H. Hong, R. H. Grubbs, Org. Lett. 2007, 9, 1955-1957.
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2, removal of ruthenium by-products from olefin metathesis products is possible by simple aqueous extraction; see: S. H. Hong, R. H. Grubbs, Org. Lett. 2007, 9, 1955-1957.
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165
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Note added in proof: For a recent attempt to solve this general problem, see:, DOI: 10.1039/b705451c
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Note added in proof: For a recent attempt to solve this general problem, see: D. Rix, F. Caïjo, I. Laurent, Ł. Gułajski, K. Grela, M. Mauduit, Chem. Commun. 2007, DOI: 10.1039/b705451c.
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