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Volumn 128, Issue 11, 2006, Pages 3508-3509

Highly active water-soluble olefin metathesis catalyst

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE; WATER;

EID: 33645394125     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja058451c     Document Type: Article
Times cited : (315)

References (28)
  • 1
    • 1442360753 scopus 로고    scopus 로고
    • Grubbs, R. H., Ed.; Wiley-VCH: Weinheim, Germany
    • (a) Handbook of Metathesis; Grubbs, R. H., Ed.; Wiley-VCH: Weinheim, Germany, 2003.
    • (2003) Handbook of Metathesis
  • 3
    • 0003476436 scopus 로고    scopus 로고
    • Cornils, B., Hermann, W. A., Eds; Wiley-VCH: Weinheim, Germany
    • Aqueous-Phase Organometallic Catalysis; Cornils, B., Hermann, W. A., Eds; Wiley-VCH: Weinheim, Germany, 2004.
    • (2004) Aqueous-Phase Organometallic Catalysis
  • 14
    • 33645384775 scopus 로고    scopus 로고
    • note
    • 2O.
  • 16
    • 27844509635 scopus 로고    scopus 로고
    • Well-ordered micelle formation of catalyst 4 aggregates in water is unlikely due to short hydrophohic chain length. For conditions of micelle formation, see: Dwars, T.; Paetzold, E.; Oehme, G. Angew. Chem. Int. Ed. 2005, 44, 7174-7199.
    • (2005) Angew. Chem. Int. Ed. , vol.44 , pp. 7174-7199
    • Dwars, T.1    Paetzold, E.2    Oehme, G.3
  • 17
    • 33645381131 scopus 로고    scopus 로고
    • note
    • Earlier work demonstrated that endo-norbornene monomers are challenging ROMP substrates when compared to exo-norbornene monomers. See refs 1 and 4.
  • 18
    • 33645414650 scopus 로고    scopus 로고
    • note
    • Catalyst 2 and 3 require 1 equiv of HCl, relative to catalyst, as a phosphine scavenger to reach their highest conversions.
  • 22
    • 33645416408 scopus 로고    scopus 로고
    • note
    • To avoid the methylidene intermediates, substituted dienes, such as N-allyleinnamylamine hydrochloride salt, were required. Using these substituted dienes is not an atom economical transformation since it has unnecessary substituents which require additional steps for preparation. Moreover, the yields of the RCM reactions with the substituted dienes using catalysis 1-3 in water were usually not good. See ref 3b.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.