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For a comprehensive survey of N-heterocyclic carbenes, see: a) W. A. Herrmann, Angew. Chem. 2002, 114, 1342; b) Angew. Chem. Int. Ed. 2002, 41, 1290;
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24
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2242492077
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unpublished results
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b) for screening of the catalytic performance of Ru- and Mo-based catalysts in cross-metathesis reactions of α,β-unsaturated sulfones and sulfoxides, see: K. Grela, M. Bieniek, M. Kim, R. Klajn, unpublished results.
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Grela, K.1
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26
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2242476014
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note
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For a comparative study of the performance of precatalysts 1b and 2 in the RCM reaction of diallyltosylamide, see: ref. [9a].
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27
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0035108849
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a) S. Randl, S. Gessler, H. Wakamatsu, S. Blechert, Synlett 2001, 430;
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30
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2242486771
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note
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Catalysts 1a, 1b, and 2 are available from Aldrich Chemical Co.
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31
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0001541522
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36
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2242472355
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note
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Extensive studies described in ref. [9a.b] suggest that a steric bulk adjacent to the chelating isopropoxy moiety of 4 and 5 is the crucial factor required for the unusually high activity of these complexes.
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37
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2242492970
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note
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For example, see footnote 32 in ref. [2g].
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38
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2242440209
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note
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We thank Mr. Michal Barbasiewicz for carrying out some preliminary AM1 calculations.
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