Synthesis, Spectroscopic Properties, and Reactivities of Bis(tosylimido)osmium(VI) Porphyrin Complexes. X-ray Crystal Structure of [OsVI(TPP)(NSO2C6H4-pCH 3)2] (TPP = Tetraphenylporphyrinato)

Inorganic Chemistry

Volumn 37, Issue 26, 1998, Pages 6564-6567

  Au, Sze Man ^a   Fung, Wai Hong ^a   Huang, Jie Sheng ^a   Cheung, Kung Kai ^a   Che, Chi Ming ^a  

^a UNIVERSITY OF HONG KONG   (Hong Kong)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000601741     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic980256u     Document Type: Article

References (32)

1. For reviews in metal- imido chemistry, see: (a) Wigley, D. E. Prog. Inorg. Chem. 1994, 42, 239. (b) Nugent, W. A.; Mayer, J. M. Metal-Ligand Multiple Bonds; Wiley-Interscience: New York, 1988.
2. For reviews in metal- imido chemistry, see: (a) Wigley, D. E. Prog. Inorg. Chem. 1994, 42, 239. (b) Nugent, W. A.; Mayer, J. M. Metal-Ligand Multiple Bonds; Wiley-Interscience: New York, 1988.
3. For metal-imido complexes as models in industrial processes, see: (a) Matta, E. A.; Du, Y. J. Am. Chem. Soc. 1988, 110, 829. (b) Mohs, T. R.; Du, Y.; Plashko, B.; Matta, E. A. J. Chem. Soc., Chem. Commun. 1997, 1707.
4. For metal-imido complexes as models in industrial processes, see: (a) Matta, E. A.; Du, Y. J. Am. Chem. Soc. 1988, 110, 829. (b) Mohs, T. R.; Du, Y.; Plashko, B.; Matta, E. A. J. Chem. Soc., Chem. Commun. 1997, 1707.
5. Breslow, R.; Gellman, S. H. J. Am. Chem. Soc. 1983, 105, 6728.
6. Alkenes aziridination catalyzed by metal-porphyrin complexes: (a) Groves, J. T.; Takahashi, T. J. Am. Chem. Soc. 1983, 105, 2073. (b) Mansuy, D.; Many, J.-P.; Dureault, A.; Bedi, G.; Battioni, P. J. Chem. Soc., Chem. Commun. 1984, 1161. (c) Mahy, J. P.; Battioni, P.; Mansuy, D. J. Am. Chem. Soc. 1986, 108, 1079. (d) Mahy, J. P.; Bedi, G.; Battioni, P.; Mansuy, D. J. Chem. Soc., Perkin Trans. 2 1988, 1517. Copper(I) complexes: (e) Evans, D. A.; Faul, M. M.; Bilodeau, M. T. J. Org. Chem. 1991, 56, 6744. Metal-salen complexes: (f) O'Connor, K. J.; Wey, S.-J.; Burrows, C. J. Tetrahedron Lett. 1992, 33, 1001.
7. Alkenes aziridination catalyzed by metal-porphyrin complexes: (a) Groves, J. T.; Takahashi, T. J. Am. Chem. Soc. 1983, 105, 2073. (b) Mansuy, D.; Many, J.-P.; Dureault, A.; Bedi, G.; Battioni, P. J. Chem. Soc., Chem. Commun. 1984, 1161. (c) Mahy, J. P.; Battioni, P.; Mansuy, D. J. Am. Chem. Soc. 1986, 108, 1079. (d) Mahy, J. P.; Bedi, G.; Battioni, P.; Mansuy, D. J. Chem. Soc., Perkin Trans. 2 1988, 1517. Copper(I) complexes: (e) Evans, D. A.; Faul, M. M.; Bilodeau, M. T. J. Org. Chem. 1991, 56, 6744. Metal-salen complexes: (f) O'Connor, K. J.; Wey, S.-J.; Burrows, C. J. Tetrahedron Lett. 1992, 33, 1001.
8. Alkenes aziridination catalyzed by metal-porphyrin complexes: (a) Groves, J. T.; Takahashi, T. J. Am. Chem. Soc. 1983, 105, 2073. (b) Mansuy, D.; Many, J.-P.; Dureault, A.; Bedi, G.; Battioni, P. J. Chem. Soc., Chem. Commun. 1984, 1161. (c) Mahy, J. P.; Battioni, P.; Mansuy, D. J. Am. Chem. Soc. 1986, 108, 1079. (d) Mahy, J. P.; Bedi, G.; Battioni, P.; Mansuy, D. J. Chem. Soc., Perkin Trans. 2 1988, 1517. Copper(I) complexes: (e) Evans, D. A.; Faul, M. M.; Bilodeau, M. T. J. Org. Chem. 1991, 56, 6744. Metal-salen complexes: (f) O'Connor, K. J.; Wey, S.-J.; Burrows, C. J. Tetrahedron Lett. 1992, 33, 1001.
9. Alkenes aziridination catalyzed by metal-porphyrin complexes: (a) Groves, J. T.; Takahashi, T. J. Am. Chem. Soc. 1983, 105, 2073. (b) Mansuy, D.; Many, J.-P.; Dureault, A.; Bedi, G.; Battioni, P. J. Chem. Soc., Chem. Commun. 1984, 1161. (c) Mahy, J. P.; Battioni, P.; Mansuy, D. J. Am. Chem. Soc. 1986, 108, 1079. (d) Mahy, J. P.; Bedi, G.; Battioni, P.; Mansuy, D. J. Chem. Soc., Perkin Trans. 2 1988, 1517. Copper(I) complexes: (e) Evans, D. A.; Faul, M. M.; Bilodeau, M. T. J. Org. Chem. 1991, 56, 6744. Metal-salen complexes: (f) O'Connor, K. J.; Wey, S.-J.; Burrows, C. J. Tetrahedron Lett. 1992, 33, 1001.
10. Alkenes aziridination catalyzed by metal-porphyrin complexes: (a) Groves, J. T.; Takahashi, T. J. Am. Chem. Soc. 1983, 105, 2073. (b) Mansuy, D.; Many, J.-P.; Dureault, A.; Bedi, G.; Battioni, P. J. Chem. Soc., Chem. Commun. 1984, 1161. (c) Mahy, J. P.; Battioni, P.; Mansuy, D. J. Am. Chem. Soc. 1986, 108, 1079. (d) Mahy, J. P.; Bedi, G.; Battioni, P.; Mansuy, D. J. Chem. Soc., Perkin Trans. 2 1988, 1517. Copper(I) complexes: (e) Evans, D. A.; Faul, M. M.; Bilodeau, M. T. J. Org. Chem. 1991, 56, 6744. Metal-salen complexes: (f) O'Connor, K. J.; Wey, S.-J.; Burrows, C. J. Tetrahedron Lett. 1992, 33, 1001.
11. Alkenes aziridination catalyzed by metal-porphyrin complexes: (a) Groves, J. T.; Takahashi, T. J. Am. Chem. Soc. 1983, 105, 2073. (b) Mansuy, D.; Many, J.-P.; Dureault, A.; Bedi, G.; Battioni, P. J. Chem. Soc., Chem. Commun. 1984, 1161. (c) Mahy, J. P.; Battioni, P.; Mansuy, D. J. Am. Chem. Soc. 1986, 108, 1079. (d) Mahy, J. P.; Bedi, G.; Battioni, P.; Mansuy, D. J. Chem. Soc., Perkin Trans. 2 1988, 1517. Copper(I) complexes: (e) Evans, D. A.; Faul, M. M.; Bilodeau, M. T. J. Org. Chem. 1991, 56, 6744. Metal-salen complexes: (f) O'Connor, K. J.; Wey, S.-J.; Burrows, C. J. Tetrahedron Lett. 1992, 33, 1001.
12. (a) Li, Z.; Conser, K. R.; Jacobsen, E. N. J. Am. Chem. Soc. 1993, 115, 5326.
13. (b) Evans, D. A.; Faul, M. M.; Bilodeau, M. T.; Anderson, B. A. Barnes, D. M. J. Am. Chem. Soc. 1993, 115, 5328.
14. (c) Noda, K.; Hosoya, N.; Irie, R.; Ito, Y.; Katsuki, T. Synlett 1993, 469.
15. (d) Evans, D. A.; Faul, M. M.; Bilodeau, M. T. J. Am. Chem. Soc. 1994, 116, 2742.
16. (e) Li, Z.; Quan, R. W.; Jacobsen, E. N. J. Am. Chem. Soc. 1995, 117, 5889.
17. Bruncko, M.; Khuong, T.-A. V.; Sharpless, K. B. Angew. Chem., Int. Ed. Engl. 1996, 35, 454.
18. Harlan, E. W.; Holm, R. H. J. Am. Chem. Soc. 1990, 112, 186.
19. Au, S. M.; Fung, W. H.; Cheng, M. C.; Che, C. M.; Peng, S. M. J. Chem. Soc., Chem. Commun. 1997, 1655.
20. Au, S. M.; Che, C. M. Unpublished results.
21. Adler, A. D.; Longo, F. R.; Finarelli, J. D.; Goldmacher, J.; Assour, J.; Korsakoff, L. J. Org. Chem. 1967, 32, 476.
22. Che, C. M.; Poon, C. K.; Chung, W. C.; Gray, H. B. Inorg. Chem. 1985, 24, 1277.
23. Yamada, Y.; Yamamoto, T.; Okawara, M. Chem. Lett. 1975, 361.
24. Che, C. M.; Lai, T. F.; Chung, W. C., Schaefer, W. P.; Gray, H. B. Inorg. Chem. 1987, 26, 3907.
25. Danopoulos, A. A.; Wilkinson, G.; Hussain-Bates, B.; Hursthouse, M. B. J. Chem. Soc., Dalton Trans. 1991, 1855.
26. Schofield, M. H.; Kee, T. P., Anhaus, J. T., Schrock, R. R.; Johnson, K. H.; Davis, W. M. Inorg. Chem. 1991, 30, 3595.
27. (a) Huang, J. S.; Che, C. M.; Poon, C. K. J. Chem. Soc., Chem. Commun. 1992, 161.
28. (b) Li, Z. Y.; Huang, J. S.; Chan, M. C. W.; Cheung, K. K.; Che, C. M. Inorg. Chem. 1997, 36, 3064.
29. Smieja, J. A.; Omberg, K. M. Inorg. Chem. 1994, 33, 614.
30. Collman, J. P.; Barnes, C. E.; Woo, L. K. Proc. Natl. Acad. Sci. U.S.A. 1983, 80, 7684.
31. Lai, T. S.; Kwong, H. L.; Che, C. M.; Peng, S. M. J. Chem. Soc., Chem. Commun. 1997, 2373.
32. Che, C. M.; Chung, W. C.; Lai, T. F. Inorg. Chem. 1988, 27, 2801.