메뉴 건너뛰기




Volumn 126, Issue 6, 2004, Pages 1794-1803

Titanium Hydrazido and Imido Complexes: Synthesis, Structure, Reactivity, and Relevance to Alkyne Hydroamination

Author keywords

[No Author keywords available]

Indexed keywords

AMINATION; AMMONIUM COMPOUNDS; AROMATIC COMPOUNDS; CATALYSTS; MONOMERS; SYNTHESIS (CHEMICAL);

EID: 1242314257     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja038320g     Document Type: Article
Times cited : (190)

References (116)
  • 3
    • 0002142225 scopus 로고
    • Ferredoxins, Hydrogenases, and Nitrogenases: Metal-Sulfide Proteins
    • Bertini, I., Gray, H. B., Lippard, S. J., Valentine, J. S., Eds.; University Science Books: Mill Valley, CA
    • (c) Stiefel, E. I.; George, G. N. Ferredoxins, Hydrogenases, and Nitrogenases: Metal-Sulfide Proteins. In Bioinorganic chemistry; Bertini, I., Gray, H. B., Lippard, S. J., Valentine, J. S., Eds.; University Science Books: Mill Valley, CA, 1994.
    • (1994) Bioinorganic Chemistry
    • Stiefel, E.I.1    George, G.N.2
  • 12
    • 3342952653 scopus 로고
    • (i) Hidai, M. Chem. Rev. 1995, 95, 1115-1133.
    • (1995) Chem. Rev. , vol.95 , pp. 1115-1133
    • Hidai, M.1
  • 18
    • 0001589060 scopus 로고
    • For a more complete discussion of hydrazido bonding and reviews, see: (a) Nugent, W. A.; Haymore, B. L. Coord. Chem. Rev. 1980, 31, 123-175.
    • (1980) Coord. Chem. Rev. , vol.31 , pp. 123-175
    • Nugent, W.A.1    Haymore, B.L.2
  • 20
    • 0001089904 scopus 로고
    • (c) Sutton, D. Chem. Rev. 1993, 93, 995-1022.
    • (1993) Chem. Rev. , vol.93 , pp. 995-1022
    • Sutton, D.1
  • 23
    • 0001206072 scopus 로고
    • For some in depth discussions of hydrazido electronic structure, see: (a) DuBois, D. L.; Hoffmann, R. Nouv. J. Chim. 1977, 1, 479-492.
    • (1977) Nouv. J. Chim. , vol.1 , pp. 479-492
    • DuBois, D.L.1    Hoffmann, R.2
  • 35
    • 0003600617 scopus 로고
    • (d) Gambarotta, S.; Floriani, C.; Chiesi-Villa, A.; Guastini, C. J. Chem. Soc., Chem. Commun. 1982, 1015-1017. For an example of a zirconium diazoalkane complex, see: Arvanitis, G. M.; Schwartz, J.; Van Engen, D. Organometallics 1986, 5, 2157-2159.
    • (1986) Organometallics , vol.5 , pp. 2157-2159
    • Arvanitis, G.M.1    Schwartz, J.2    Van Engen, D.3
  • 60
    • 0035956451 scopus 로고    scopus 로고
    • Cao, C.; Ciszewski, J. T.; Odom, A. L. Organometallics 2001, 20, 5011-5013. Cao, C.; Ciszewski, J. T.; Odom, A. L. Organometallics 2002, 21, 5148.
    • (2001) Organometallics , vol.20 , pp. 5011-5013
    • Cao, C.1    Ciszewski, J.T.2    Odom, A.L.3
  • 61
  • 64
    • 0035907836 scopus 로고    scopus 로고
    • We are assuming a mechanism comparable to that of Group-4 catalysis using primary amines. For references on amine hydroamination, see: (a) Pohlki, F.; Doye, S. Angew. Chem., Int. Ed. Engl. 2001, 40, 2305-2308.
    • (2001) Angew. Chem., Int. Ed. Engl. , vol.40 , pp. 2305-2308
    • Pohlki, F.1    Doye, S.2
  • 76
    • 0000788623 scopus 로고    scopus 로고
    • For an excellent review of hydroamination chemistry, see: (a) Muller, T. E.; Beller, M. Chem. Rev. 1998, 98, 675-703.
    • (1998) Chem. Rev. , vol.98 , pp. 675-703
    • Muller, T.E.1    Beller, M.2
  • 77
    • 0037355249 scopus 로고    scopus 로고
    • For a unique perspective on the field titanium hydroamination, see: (b) Bytschkov, I.; Doye, S. Eur. J. Org. Chem. 2003, 935-946.
    • (2003) Eur. J. Org. Chem. , pp. 935-946
    • Bytschkov, I.1    Doye, S.2
  • 79
    • 0000602079 scopus 로고
    • Review of transition metal imido complexes, see: Wigley, D. E. Prog. Inorg. Chem. 1994, 42, 239-482.
    • (1994) Prog. Inorg. Chem. , vol.42 , pp. 239-482
    • Wigley, D.E.1
  • 97
    • 0003600638 scopus 로고
    • (p) Trösch, D. J. M.; Collier, P. E.; Bashall, A.; Gade, L. H.; McPartlin, M.; Mountford, P.; Radojevic, S. Organometallics 2001, 20, 3308-3313. Thorn, D. L.; Nugent, W. A.; Harlow, R. L. J. Am. Chem. Soc. 1981, 103, 357-363.
    • (1981) J. Am. Chem. Soc. , vol.103 , pp. 357-363
    • Thorn, D.L.1    Nugent, W.A.2    Harlow, R.L.3
  • 99
    • 84980144433 scopus 로고
    • No terminal titanium hydrazido(2-) complexes are found in the latest Cambridge Structural Database at the time of this writing. For examples of structurally characterized terminal hydrazido(2-) compounds of the Group-5 elements, see: (a) Veith, M. Angew. Chem., Int. Ed. Engl. 1976, 15, 387.
    • (1976) Angew. Chem., Int. Ed. Engl. , vol.15 , pp. 387
    • Veith, M.1
  • 104
    • 0007920902 scopus 로고    scopus 로고
    • 3 are known. They have been given the moniker "hydrazidium" previously, which misleadingly has the "ium" ending for a ligand with an overall negative charge. Consequently, we chose an alternative nomenclature derived from N-ammonium imido. The only N-ammonium imido titanium complexes in the literature are pyridinium imido derivatives, see: (a) Retbøll, M.; Ishii, Y.; Hidai, M. Organometallics 1999, 18, 150-155.
    • (1999) Organometallics , vol.18 , pp. 150-155
    • Retbøll, M.1    Ishii, Y.2    Hidai, M.3
  • 116
    • 85039566196 scopus 로고    scopus 로고
    • note
    • 2), which bears two electron-deficient thiolates, as an alternative hydrazine hydroamination catalyst, see ref 18.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.