Large ground-state entropy changes for hydrogen atom transfer reactions of iron complexes

Journal of the American Chemical Society

Volumn 129, Issue 16, 2007, Pages 5153-5166

  Mader, Elizabeth A ^a   Davidson, Ernest R ^a   Mayer, James M ^a  

^a UNIVERSITY OF WASHINGTON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

HYDROXYLAMINE; PROTON COUPLED ELECTRON TRANSFER (PCET); SOLVENT EFFECTS; TRANSITION METAL CENTERS;

AMINES; ENTROPY; GROUND STATE; HYDROGEN; HYDROGEN BONDS; REACTION KINETICS; TRANSPORT PROPERTIES;

METAL COMPLEXES;

HYDROGEN; HYDROXYLAMINE; IRON COMPLEX; IRON TRIS(2,2' BI 1,4,5,6 TETRAHYDROPYRIMIDINE)DIPERCHLORATE; IRON TRIS(2,2' BI 2 IMIDAZOLINE)DIPERCHLORATE; TEMPOL; TRANSITION ELEMENT; UNCLASSIFIED DRUG;

ARTICLE; DISSOCIATION; ELECTRON TRANSPORT; ENERGY; ENTHALPY; ENTROPY; HYDROGEN BOND; KINETICS; OXIDATION; SOLVENT EFFECT; THERMODYNAMICS;

ENTROPY; FERROUS COMPOUNDS; HYDROGEN; KINETICS; SOLVENTS;

EID: 34247515508     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0686918     Document Type: Article

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