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Volumn 126, Issue 26, 2004, Pages 8066-8067

Hydrogen atom transfer from iron(II)-tris[2,2′- bi(tetrahydropyrimidine)] to TEMPO: A negative enthalpy of activation predicted by the Marcus equation

Author keywords

[No Author keywords available]

Indexed keywords

FERROUS ION; HYDROGEN; HYDROXYLAMINE; PYRIMIDINE DERIVATIVE;

EID: 3042811583     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja049246k     Document Type: Article
Times cited : (58)

References (30)
  • 6
    • 3042782213 scopus 로고    scopus 로고
    • note
    • That eq 1 is a concerted H-atom transfer (PCET) reaction is based on thermochemical arguments2,3 that will appear in the upcoming full report.
  • 9
    • 3042786769 scopus 로고    scopus 로고
    • note
    • Full details are provided in the Supporting Information. Rate and equilibrium constants are not statistically corrected.
  • 19
    • 4043114730 scopus 로고
    • (b) The more thorough treatment in Marcus, R. A.; Sutin, N. Comments Inorg. Chem. 1986, 5, 119-133 assumes δλ/δT = 0 and δΔ‡H/δT ≠ 0, opposite to the experimental Eyring and van't Hoff analyses in this system.
    • (1986) Comments Inorg. Chem. , vol.5 , pp. 119-133
    • Marcus, R.A.1    Sutin, N.2
  • 23
    • 3042783731 scopus 로고    scopus 로고
    • note
    • 7T°(4-oxo-TEMPO + TEMPOH).
  • 27
    • 3042743039 scopus 로고    scopus 로고
    • Submitted for publication
    • (b) Rhile, I. J.; Mayer, J. M. Submitted for publication, 2004.
    • (2004)
    • Rhile, I.J.1    Mayer, J.M.2
  • 29
    • 3042745936 scopus 로고    scopus 로고
    • Mayer, J. M. In ref 1a; pp 1-45
    • (b) Mayer, J. M. In ref 1a; pp 1-45.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.