Proton and hydrogen atom tunnelling in hydrolytic and redox enzyme catalysis

Canadian Journal of Chemistry

Volumn 77, Issue 5-6, 1999, Pages 1085-1096

  Kuznetsov, A M ^a   Ulstrup, Jens ^b  

^a FRUMKIN INSTITUTE OF PHYSICAL CHEMISTRY AND ELECTROCHEMISTRY   (Russian Federation)

^b TECHNICAL UNIVERSITY OF DENMARK   (Denmark)

Author keywords

Gated proton transfer; Generalized Born Oppenheimer scheme; Kinetic isotope effect; Partially adiabatic proton transfer; Proton tunnelling in enzyme catalysis

Indexed keywords

ENZYME; HYDROGEN; ISOTOPE; LIPOXYGENASE; PROTON;

ARTICLE; CATALYSIS; CHEMICAL REACTION KINETICS; ENERGY TRANSFER; ENZYME MECHANISM; HYDROLYSIS; MOLECULAR DYNAMICS; OXIDATION REDUCTION REACTION; PROTON TRANSPORT; TEMPERATURE DEPENDENCE;

ACTIVATION ENERGY; ATOMS; BODY FLUIDS; CARRIER MOBILITY; CATALYSIS; ENZYMES; FREE ENERGY; GIBBS FREE ENERGY; HYDROGEN; ISOTOPES; MAMMALS; PROTON TRANSFER; TEMPERATURE DISTRIBUTION;

BORN-OPPENHEIMER; ENZYME CATALYSIS; GATED PROTON TRANSFER; GENERALIZED BORN; GENERALIZED BORN–OPPENHEIME SCHEME; HYDROGEN TRANSFER; KINETIC ISOTOPES EFFECTS; PARTIALLY ADIABATIC PROTON TRANSFER; PROTON TUNNELING; PROTON TUNNELING IN ENZYME CATALYSE;

RATE CONSTANTS;

EID: 0033305793     PISSN: 00084042     EISSN: None     Source Type: Journal    
DOI: 10.1139/cjc-77-5-6-1085     Document Type: Article

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