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Volumn 106, Issue 8, 2002, Pages 2009-2017

Electrochemical activation parameters of coupled electron-transfer and spin-exchange reactions. Experimental studies of [M(Tacn)2]3+/2+ and [Fe(Pzb)2]+/0 redox systems

Author keywords

[No Author keywords available]

Indexed keywords

ELECTROCHEMICAL ACTIVATIONS;

EID: 0037187144     PISSN: 10895647     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp013294z     Document Type: Article
Times cited : (22)

References (86)
  • 6
    • 0000472834 scopus 로고
    • Wilkinson, G., Gillard, R.D., McCleverty, J.A., Eds.; Pergamon Press: Oxford; Chapter 7.2
    • Meyer, T.J.; Taube, H. In Comprehensive Coordination Chemistry, Wilkinson, G., Gillard, R.D., McCleverty, J.A., Eds.; Pergamon Press: Oxford, 1987; Volume 1, Chapter 7.2.
    • (1987) Comprehensive Coordination Chemistry , vol.1
    • Meyer, T.J.1    Taube, H.2
  • 47
    • 77956809096 scopus 로고
    • Compton, R.G., Ed.; Elsevier: Amsterdam
    • Weaver, M.J. In Comprehensive Chemical Kinetics; Compton, R.G., Ed.; Elsevier: Amsterdam, 1987; Volume 27, pp 1-60.
    • (1987) Comprehensive Chemical Kinetics , vol.27 , pp. 1-60
    • Weaver, M.J.1
  • 48
    • 0011167208 scopus 로고    scopus 로고
    • note
    • Derivations are presented for a LS-M(III) → HS-M(II) conversion, because this circumstance corresponds to the more frequent observation (based on ligand field strength considerations) that low-spin behavior is favored in the higher oxidation state and high-spin behavior is favored in the lower oxidation state.
  • 51
    • 0011235232 scopus 로고    scopus 로고
    • note
    • This assumption is based on the expectation that inner-shell reorganization energies will be small and energy barriers will be symmetric for electrode reactions involving a single spin-state. The transfer coefficient will be close to 0.5 under these circumstances.
  • 52
    • 0011211273 scopus 로고    scopus 로고
    • note
    • 2- is the hexadentate Schiff base ligand prepared by condensation of salicylaldehyde and triethylenetetramine.
  • 62
    • 0011231565 scopus 로고    scopus 로고
    • note
    • L is included in eq 23.
  • 68
    • 0011174081 scopus 로고    scopus 로고
    • note
    • 28.
  • 83
    • 0011249020 scopus 로고    scopus 로고
    • note
    • 20.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.