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Derivations are presented for a LS-M(III) → HS-M(II) conversion, because this circumstance corresponds to the more frequent observation (based on ligand field strength considerations) that low-spin behavior is favored in the higher oxidation state and high-spin behavior is favored in the lower oxidation state.
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51
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This assumption is based on the expectation that inner-shell reorganization energies will be small and energy barriers will be symmetric for electrode reactions involving a single spin-state. The transfer coefficient will be close to 0.5 under these circumstances.
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2- is the hexadentate Schiff base ligand prepared by condensation of salicylaldehyde and triethylenetetramine.
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L is included in eq 23.
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