C-F bond activation by modified sulfinatodehalogenation: Facile synthesis and properties of novel tetrafluorobenzoporphyrins by direct intramolecular cyclization and reductive defluorinative aromatization of readily available β-perfluoroalkylated porphyrins

Journal of Organic Chemistry

Volumn 71, Issue 26, 2006, Pages 9772-9783

  Liu, Chao ^a   Shen, Dong Mei ^a   Zeng, Zhuo ^b   Guo, Can Cheng ^c   Chen, Qing Yun ^a,c  

^a SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

^b SOUTH CHINA NORMAL UNIVERSITY   (China)

^c HUNAN UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

AROMATIZATION; CHEMICAL BONDS; CRYSTAL STRUCTURE; ELECTROCHEMISTRY; POSITIVE IONS; REACTION KINETICS; SODIUM COMPOUNDS; SYNTHESIS (CHEMICAL);

BOND ACTIVATION; DEFLUORINATIVES; INTRAMOLECULAR CYCLIZATION; SULFINATODEHALOGENATION;

PORPHYRINS;

ALKYL GROUP; BENZOPORPHYRIN DERIVATIVE; DIMETHYL SULFOXIDE; METAL ION; PALLADIUM; PERFLUORO COMPOUND; POTASSIUM CARBONATE; SODIUM DITHIONITE; SODIUM SULFATE;

AROMATIZATION; ARTICLE; CATALYSIS; CHEMICAL BOND; CROSS COUPLING REACTION; CYCLIZATION; DEHALOGENATION; ELECTROCHEMICAL ANALYSIS; FLUORINATION; QUANTUM YIELD; REACTION ANALYSIS; REDUCTION; SULFINATODEHALOGENATION; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

CRYSTALLOGRAPHY, X-RAY; CYCLIZATION; FLUORINE; METALS, HEAVY; MODELS, MOLECULAR; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; OXIDATION-REDUCTION; PORPHYRINS;

EID: 33846013959     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo061743r     Document Type: Article

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