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Volumn 125, Issue 19, 2003, Pages 5646-5647

Ni- or Cu-catalyzed cross-coupling reaction of alkyl fluorides with grignard reagents

Author keywords

[No Author keywords available]

Indexed keywords

ALKANE DERIVATIVE; ALKYL GROUP; BROMINE; BROMINE DERIVATIVE; COPPER; FLUORIDE; HALIDE; MAGNESIUM; METAL COMPLEX; NICKEL;

EID: 0037620634     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja034201p     Document Type: Article
Times cited : (257)

References (29)
  • 27
    • 0037798846 scopus 로고    scopus 로고
    • note
    • 3 are 112, 85, 74 kcal/mol for X = F, Cl, Br, respectively. Energy differences between these two bonds for F, Cl, Br are similar (30, 28, 27 kcal/mol, respectively), indicating that the reaction of alkyl fluorides is not disfavored energetically.
  • 28
    • 0034596340 scopus 로고    scopus 로고
    • N2 mechanism. A theoretical study proposed a cyclic transition state having an RX-Li interaction, which facilitates R-X bond cleavage in the rate-determining step: Nakamura, E.; Mori, S.; Morokuma, K. J. Am. Chem. Soc. 2000, 122, 7294-7307.
    • (2000) J. Am. Chem. Soc. , vol.122 , pp. 7294-7307
    • Nakamura, E.1    Mori, S.2    Morokuma, K.3
  • 29
    • 0033582676 scopus 로고    scopus 로고
    • -1 (at 25 °C) for the isomerization of the 6,6-diphenyl-5-hexenyl radical to the cyclopentyldiphenylmethyl radical has been reported: Newcomb, M.; Choi, S.-Y.; Horner, J. H. J. Org. Chem. 1999, 64, 1225-1231.
    • (1999) J. Org. Chem. , vol.64 , pp. 1225-1231
    • Newcomb, M.1    Choi, S.-Y.2    Horner, J.H.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.