Carbon-fluorine bond activation coupled with carbon-carbon bond formation at iridium. Confirmation of complete kinetic diastereoselectivity at the new carbon stereocenter by intramolecular trapping using vinyl as the migrating group

Journal of the American Chemical Society

Volumn 127, Issue 17, 2005, Pages 6325-6334

  Hughes, Russell P ^a   Laritchev, Roman B ^a   Zakharov, Lev N ^b   Rheingold, Arnold L ^b  

^a Dartmouth College   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ANALYSIS; CHEMICAL BONDS; FLUORINE; ISOMERS; NUCLEAR MAGNETIC RESONANCE; REACTION KINETICS; STEREOCHEMISTRY; X RAY CRYSTALLOGRAPHY;

BOND FORMATION; COUPLING REACTIONS; LUTIDINIUM;

CARBON;

CARBON; FLUORINE; IRIDIUM; VINYL DERIVATIVE;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION KINETICS; COMPLEX FORMATION; CONFORMATIONAL TRANSITION; DRUG ISOLATION; NUCLEAR MAGNETIC RESONANCE; STEREOCHEMISTRY; THERMODYNAMICS; X RAY CRYSTALLOGRAPHY;

EID: 18244366917     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja042345d     Document Type: Article

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