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Volumn 118, Issue 7, 1996, Pages 1805-1806

Group IV metallocene-mediated synthesis of fluoroaromatics via selective defluorination of saturated perfluorocarbons

Author keywords

[No Author keywords available]

Indexed keywords

ORGANOFLUORINE DERIVATIVE;

EID: 0029879688     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja952563u     Document Type: Article
Times cited : (145)

References (33)
  • 2
    • 0003132813 scopus 로고
    • Chemistry of Organic Fluorine Compounds II. A Critical Review
    • American Chemical Society: Washington, DC. and references therein
    • (b) Chemistry of Organic Fluorine Compounds II. A Critical Review; Hudlicky, M., Pavlath, A. E., Eds.; ACS Monograph 187; American Chemical Society: Washington, DC. 1995; and references therein.
    • (1995) ACS Monograph 187
    • Hudlicky, M.1    Pavlath, A.E.2
  • 15
    • 85033097351 scopus 로고
    • Inorganic Fluorine Chemistry: Toward the 21st Century; Thrasher, J. S., Strauss, S. H., Eds ; American Chemical Society: Washington, DC
    • (b) Weydert, M.; Andersen, R. A. In Inorganic Fluorine Chemistry: Toward the 21st Century; Thrasher, J. S., Strauss, S. H., Eds ; ACS Symposium Series 555, American Chemical Society: Washington, DC. 1994: pp 383-391.
    • (1994) ACS Symposium Series 555 , pp. 383-391
    • Weydert, M.1    Andersen, R.A.2
  • 21
    • 0000944975 scopus 로고
    • 2 see: (a) Kablaoui, N M ; Buchwald, S. L. J. Am. Chem. Soc. 1995, 117, 6785-6786 (b) Crowe, W E., Rachita, M. J. J. Am. Chem. Soc. 1995, 117, 6787-6788.
    • (1995) J. Am. Chem. Soc. , vol.117 , pp. 6785-6786
    • Kablaoui, N.M.1    Buchwald, S.L.2
  • 22
    • 0000767710 scopus 로고
    • 2 see: (a) Kablaoui, N M ; Buchwald, S. L. J. Am. Chem. Soc. 1995, 117, 6785-6786 (b) Crowe, W E., Rachita, M. J. J. Am. Chem. Soc. 1995, 117, 6787-6788.
    • (1995) J. Am. Chem. Soc. , vol.117 , pp. 6787-6788
    • Crowe, W.E.1    Rachita, M.J.2
  • 23
    • 13344250070 scopus 로고    scopus 로고
    • note
    • Integration of the crude reaction mixture was performed using fluorobenzene as an internal standard. The perfluoronaphthalene was isolated following chromatography on silica with pentane. The fraction was collected, and rotatory evaporation yielded 0.665 g (2.44 mmol. 4%) of White crystalline perfluoronaphthalene.
  • 24
    • 13344284259 scopus 로고    scopus 로고
    • note
    • 19F NMR spectroscopy using added fluorobenzene as an internal standard.
  • 26
    • 13344283027 scopus 로고    scopus 로고
    • note
    • 19F NMR spectroscopy. A control experiment showed that there is no reaction between n-BuLi and perfluorodecalin.
  • 31
    • 13344249359 scopus 로고    scopus 로고
    • note
    • 19F NMR spectroscopy using added fluorobenzene as an internal standard.


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