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Volumn 110, Issue 27, 2006, Pages 13326-13351

Oxide- and zeolite-supported molecular metal complexes and clusters: Physical characterization and determination of structure, bonding, and metal oxidation state

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSTS; CHEMICAL BONDS; COMPLEXATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXIDATION; ZEOLITES;

EID: 33746403318     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp0571123     Document Type: Article
Times cited : (118)

References (167)
  • 1
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    • (1997)
    • Walzer Jr., J.F.1
  • 12
    • 33746455116 scopus 로고
    • Anderson, J. R., Boudart, M., Eds; Springer-Verlag; Heidelberg
    • Peri, J. B. In Catalysis - Science and Technology; Anderson, J. R., Boudart, M., Eds; Springer-Verlag; Heidelberg, 1984; Vol. 5, p 176.
    • (1984) Catalysis - Science and Technology , vol.5 , pp. 176
    • Peri, J.B.1
  • 19
    • 33746449161 scopus 로고
    • Gates, B. C., Guczi, L., Knözinger, H., Eds.; Elsevier: Amsterdam
    • Knözinger, H. In Metal Clusters in Catalysis; Gates, B. C., Guczi, L., Knözinger, H., Eds.; Elsevier: Amsterdam, 1986; p 178.
    • (1986) Metal Clusters in Catalysis , pp. 178
    • Knözinger, H.1
  • 29
    • 84906401064 scopus 로고    scopus 로고
    • note
    • The spectroscopic and microscopic methods referred to here are for the most part well established and used in the investigation of catalysts. Only a few details are included here to address the specific requirements of the applications to supported metal complexes and clusters. However, we emphasize that X-ray absorption spectroscopy is still a developing technique, which has been improving, with the capabilities offered by synchrotrons. X-ray absorption spectroscopy is still less readily available to researchers than most of the other techniques described here, in part because of the need for specialized equipment for sample handling at a synchrotron and in part because of the challenges of data fitting. Analysis of EXAFS and XANES data is not entirely straightforward, requiring chemical insight in the choice of candidate structures. Therefore, to help readers develop an understanding of the X-ray absorption characterization methods discussed below, further details of this technique are provided in the Appendix.
  • 35
    • 33746427481 scopus 로고
    • Gates, B. C., Guczi, L., Knözinger, H., Eds.; Elsevier: Amsterdam
    • Knözinger, H. In Metal Clusters in Catalysis; Gates, B. C., Guczi, L., Knözinger, H., Eds.; Elsevier: Amsterdam, 1986; pp 259-263.
    • (1986) Metal Clusters in Catalysis , pp. 259-263
    • Knözinger, H.1
  • 54
    • 84906372311 scopus 로고    scopus 로고
    • Bhirud, V. A.; Uzun, A.; Lobo, R. J.; Gates, B. C. to be published
    • Bhirud, V. A.; Uzun, A.; Lobo, R. J.; Gates, B. C. to be published.
  • 56
    • 84906401063 scopus 로고    scopus 로고
    • note
    • 58
  • 91
    • 33746411894 scopus 로고
    • Gates, B. C., Guczi, L., Knözinger, H., Eds.; Elsevier: Amsterdam
    • Knözinger, H. In Metal Clusters in Catalysis; Gates, B. C., Guczi, L., Knözinger, H., Eds.; Elsevier: Amsterdam, 1986; pp 156-158.
    • (1986) Metal Clusters in Catalysis , pp. 156-158
    • Knözinger, H.1
  • 114
    • 84906372312 scopus 로고    scopus 로고
    • note
    • 116-118 Moreover, in all the theoretical calculations carried out in attempts to consider the effect of the support on the XANES, it has been assumed that all the supported clusters are located at equivalent sites, which might be a significant oversimplification. More work is needed on the theory of XANES for interpretation and prediction of the spectra of samples containing extremely small structures on supports.
  • 147
    • 84906386445 scopus 로고    scopus 로고
    • Li, F.; Yu, P.; Hartl, M.; Daemen, L. L.; Eckert, J.; Gates, B. C., to be published
    • Li, F.; Yu, P.; Hartl, M.; Daemen, L. L.; Eckert, J.; Gates, B. C., to be published.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.