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2 concentration. The area under the TCD signal and the baseline were calculated by using the software TPCv.4.11, Advanced Scientific Design, Inc., which extrapolates the baseline (with a linear fitting) from 10 to 30 K before any change of about 5% (peak) is detected in the TCD signal.
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However, we do not rule out the possibility that a small fraction of the gold could be present as cationic gold, either as Au(III) or Au(I).
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