Perhydrocarbyl ReVII complexes: Comparison of molecular and surface complexes

Journal of the American Chemical Society

Volumn 125, Issue 2, 2003, Pages 492-504

  Chabanas, Mathieu ^a   Baudouin, Anne ^a   Copéret, Christophe ^a   Basset, Jean Marie ^a   Lukens, Wayne ^b   Lesage, Anne ^c   Hediger, Sabine ^c   Emsley, Lyndon ^c  

^a UMR 5265   (France)

^b LAWRENCE BERKELEY NATIONAL LABORATORY   (United States)

^c UNIVERSITÉ DE LYON   (France)

Author keywords

[No Author keywords available]

Indexed keywords

CORDINATION SPHERE; MOLECULAR COMPLEXES;

CARBON; ISOMERS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SILICA;

ORGANIC COMPOUNDS;

RHENIUM COMPLEX; SILICON DIOXIDE;

ARTICLE; CHEMICAL BINDING; COMPARATIVE STUDY; COMPLEX FORMATION; NUCLEAR MAGNETIC RESONANCE; PHOTOCHEMISTRY; REACTION ANALYSIS; STRUCTURE ANALYSIS; THERMAL ANALYSIS;

EID: 0037438683     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja020136s     Document Type: Article

References (35)

1. For the preparation of 1a, see: (a) Edwards, D. S.; Biondi, L. V.; Ziller, J. W.; Churchill, M. R.; Schrock, R. R. Organometallics 1983, 2, 1505. (b) Toreki, R.; Schrock, R. R.; Davis, W. M. J. Am. Chem. Soc. 1992, 114, 3367.
2. For the preparation of 1a, see: (a) Edwards, D. S.; Biondi, L. V.; Ziller, J. W.; Churchill, M. R.; Schrock, R. R. Organometallics 1983, 2, 1505. (b) Toreki, R.; Schrock, R. R.; Davis, W. M. J. Am. Chem. Soc. 1992, 114, 3367.
3. Chabanas, M.; Baudouin, A.; Copéret, C.; Basset, J.-M. J. Am. Chem. Soc. 2001, 123, 2062.
4. 2-(700).
5. By "neopentyl-like", we mean either neopentyl-, neopentylidene-, or neopentylidyne-type ligands.
6. (a) Petroff Saint-Arroman, R.; Chabanas, M.; Copéret, C.; Basset, J.-M.; Lesage, A.; Emsley, L. J. Am. Chem. Soc. 2001, 123, 3082. (b) Chabanas, M.; Quadrelli, A.; Copéret, C.; Thivolle-Cazat, J.; Basset, B.; Fenet, J.-M.; Lesage, A.; Emsley, L. Angew. Chem., Int. Ed. 2001, 43, 4493.
7. (a) Petroff Saint-Arroman, R.; Chabanas, M.; Copéret, C.; Basset, J.-M.; Lesage, A.; Emsley, L. J. Am. Chem. Soc. 2001, 123, 3082. (b) Chabanas, M.; Quadrelli, A.; Copéret, C.; Thivolle-Cazat, J.; Basset, B.; Fenet, J.-M.; Lesage, A.; Emsley, L. Angew. Chem., Int. Ed. 2001, 43, 4493.
8. Derome, A. E. Modern NMR Techniques for Chemistry Research; Organic Chemistry Series Vol. 6; Pergamon Press: Oxford, 1987.
9. For Re-O, Re=C, and Re≡C bond distances, see: (a) ref 1. (b) Cai, S.; Hoffman, D. M.; Wierda, D. A. J. Chem. Soc., Chem. Commun. 1988, 1489. (c) Toreki, R.; Schrock, R. R.; Vale, M. G. J. Am. Chem. Soc. 1991, 113, 3610. (d) Toreki, R.; Vaughan, G. A.; Schrock, R. R.; Davis, W. M. J. Am. Chem. Soc. 1993, 115, 127.
10. For Re-O, Re=C, and Re≡C bond distances, see: (a) ref 1. (b) Cai, S.; Hoffman, D. M.; Wierda, D. A. J. Chem. Soc., Chem. Commun. 1988, 1489. (c) Toreki, R.; Schrock, R. R.; Vale, M. G. J. Am. Chem. Soc. 1991, 113, 3610. (d) Toreki, R.; Vaughan, G. A.; Schrock, R. R.; Davis, W. M. J. Am. Chem. Soc. 1993, 115, 127.
11. For Re-O, Re=C, and Re≡C bond distances, see: (a) ref 1. (b) Cai, S.; Hoffman, D. M.; Wierda, D. A. J. Chem. Soc., Chem. Commun. 1988, 1489. (c) Toreki, R.; Schrock, R. R.; Vale, M. G. J. Am. Chem. Soc. 1991, 113, 3610. (d) Toreki, R.; Vaughan, G. A.; Schrock, R. R.; Davis, W. M. J. Am. Chem. Soc. 1993, 115, 127.
12. For Re-O, Re=C, and Re≡C bond distances, see: (a) ref 1. (b) Cai, S.; Hoffman, D. M.; Wierda, D. A. J. Chem. Soc., Chem. Commun. 1988, 1489. (c) Toreki, R.; Schrock, R. R.; Vale, M. G. J. Am. Chem. Soc. 1991, 113, 3610. (d) Toreki, R.; Vaughan, G. A.; Schrock, R. R.; Davis, W. M. J. Am. Chem. Soc. 1993, 115, 127.
13. For a Re-C bond distance, see ref 7b.
14. Schofield, M. H.; Schrock, R. R.; Park, L. Y. Organometallics 1991, 10, 1844. See also refs 1a and 7d.
15. Similar observations have been made on other grafted organometallic complexes, see: Corker, J.; Lefebvre, F.; Lécuyer, C.; Dufaud. V.; Quignard, F.; Choplin, A.; Evans, J.; Basset, J.-M. Science 1996, 271, 966. Vidal, V.; Théolier, A.; Thivolle-Cazat, J.; Basset, J.-M.; Corker, J. J. Am. Chem. Soc. 1996, 118, 4595.
16. Similar observations have been made on other grafted organometallic complexes, see: Corker, J.; Lefebvre, F.; Lécuyer, C.; Dufaud. V.; Quignard, F.; Choplin, A.; Evans, J.; Basset, J.-M. Science 1996, 271, 966. Vidal, V.; Théolier, A.; Thivolle-Cazat, J.; Basset, J.-M.; Corker, J. J. Am. Chem. Soc. 1996, 118, 4595.
17. VI: Oskam, J. H.; Schrock, R. R. J. Am. Chem. Soc. 1993, 115, 11831. See also: LaPointe, A. M.; Schrock, R. R.; Davis, W. M. J. Am. Chem. Soc. 1995, 117, 4802 and references therein.
18. VI: Oskam, J. H.; Schrock, R. R. J. Am. Chem. Soc. 1993, 115, 11831. See also: LaPointe, A. M.; Schrock, R. R.; Davis, W. M. J. Am. Chem. Soc. 1995, 117, 4802 and references therein.
19. tBu signal of syn-2b (44 ppm). The extra peak at 68 ppm is probably due to a partial decomposition of the product because it does not appear reproducibly.
20. The actual temperature in the probe is probably much higher that the one fixed (> 100 °C).
21. Schrock, R. R.; Clark, D. N.; Sancho, J.; Wengrovius, J. H.; Rocklage, S.; Pedersen, S. F. Organometallics 1982, 1, 4802. Caulton, K. G.; Chilsom, M. H.; Streib, W. E.; Xue, Z. J. Am. Chem. Soc. 1991, 113, 6082. Lapointe, A. M.; Schrock, R. R.; Davis, W. M. J. Am. Chem. Soc. 1995, 117, 4802, Li, L.; Hung, M.; Xue, Z. J. Am. Chem. Soc. 1995, 117, 12746, Chen, T.; Wu, Z.; Li. L.; Sorasaenee, K. R.; Diminie, J. B.; Pan, H.; Guzei, I. A.; Rheingold, A. L.; Xue, Z. J. Am. Chem. Soc. 1998, 120, 13519.
22. Schrock, R. R.; Clark, D. N.; Sancho, J.; Wengrovius, J. H.; Rocklage, S.; Pedersen, S. F. Organometallics 1982, 1, 4802. Caulton, K. G.; Chilsom, M. H.; Streib, W. E.; Xue, Z. J. Am. Chem. Soc. 1991, 113, 6082. Lapointe, A. M.; Schrock, R. R.; Davis, W. M. J. Am. Chem. Soc. 1995, 117, 4802, Li, L.; Hung, M.; Xue, Z. J. Am. Chem. Soc. 1995, 117, 12746, Chen, T.; Wu, Z.; Li. L.; Sorasaenee, K. R.; Diminie, J. B.; Pan, H.; Guzei, I. A.; Rheingold, A. L.; Xue, Z. J. Am. Chem. Soc. 1998, 120, 13519.
23. Schrock, R. R.; Clark, D. N.; Sancho, J.; Wengrovius, J. H.; Rocklage, S.; Pedersen, S. F. Organometallics 1982, 1, 4802. Caulton, K. G.; Chilsom, M. H.; Streib, W. E.; Xue, Z. J. Am. Chem. Soc. 1991, 113, 6082. Lapointe, A. M.; Schrock, R. R.; Davis, W. M. J. Am. Chem. Soc. 1995, 117, 4802, Li, L.; Hung, M.; Xue, Z. J. Am. Chem. Soc. 1995, 117, 12746, Chen, T.; Wu, Z.; Li. L.; Sorasaenee, K. R.; Diminie, J. B.; Pan, H.; Guzei, I. A.; Rheingold, A. L.; Xue, Z. J. Am. Chem. Soc. 1998, 120, 13519.
24. Schrock, R. R.; Clark, D. N.; Sancho, J.; Wengrovius, J. H.; Rocklage, S.; Pedersen, S. F. Organometallics 1982, 1, 4802. Caulton, K. G.; Chilsom, M. H.; Streib, W. E.; Xue, Z. J. Am. Chem. Soc. 1991, 113, 6082. Lapointe, A. M.; Schrock, R. R.; Davis, W. M. J. Am. Chem. Soc. 1995, 117, 4802, Li, L.; Hung, M.; Xue, Z. J. Am. Chem. Soc. 1995, 117, 12746, Chen, T.; Wu, Z.; Li. L.; Sorasaenee, K. R.; Diminie, J. B.; Pan, H.; Guzei, I. A.; Rheingold, A. L.; Xue, Z. J. Am. Chem. Soc. 1998, 120, 13519.
25. Schrock, R. R.; Clark, D. N.; Sancho, J.; Wengrovius, J. H.; Rocklage, S.; Pedersen, S. F. Organometallics 1982, 1, 4802. Caulton, K. G.; Chilsom, M. H.; Streib, W. E.; Xue, Z. J. Am. Chem. Soc. 1991, 113, 6082. Lapointe, A. M.; Schrock, R. R.; Davis, W. M. J. Am. Chem. Soc. 1995, 117, 4802, Li, L.; Hung, M.; Xue, Z. J. Am. Chem. Soc. 1995, 117, 12746, Chen, T.; Wu, Z.; Li. L.; Sorasaenee, K. R.; Diminie, J. B.; Pan, H.; Guzei, I. A.; Rheingold, A. L.; Xue, Z. J. Am. Chem. Soc. 1998, 120, 13519.
26. 13C).
27. 8, see: Lapointe, A. M.; Schrock, R. R. Organometallics 1995, 14, 1875.
28. 2, the alkylidyne ligand was found to behave in most cases as an ancillary ligand, see ref 7c.
29. D of 2 and 7 would lead to our case of F equal to 66 and 69%. respectively, to be compared with 61 % assuming no isotope effect.
30. Schrock, R. R.; Crowe, W. E.; Bazan, G. C.; DiMare, M.; O'Regan, M. B.; Schofield, M. H. Organometallics 1991, 10, 1832. See also ref 1b.
31. Chabanas, M. Ph.D. Thesis. Université Claude Bernard Lyon 1, 2001.
32. Perrin, D. D.; Armarego, W. L. F.; Perrin, D. R. Purification of Laboratory Chemicals; Pergamon Press: New York, 1980.
33. Marion, D.; Wütrich, K. Biochem. Biophys. Res. Commun. 1983, 113, 967.
34. Koningsberger, D. C.; Prins, R. X-ray Absorption: Principles, Applications, Techniques of EXAFS, SEXAFS, and XANES; John Wiley & Sons: New York, 1988.
35. Ankudinov, A.; Ravel, B.; Rehr, J. J.; Conradson, S. Phys. Rev. 1998, B58, 7565.