Detailed structural investigation of the grafting of [Ta(=CHtBu)(CH 2tBu)3] and [Cp*TaMe4] on silica partially dehydroxylated at 700 °C and the activity of the grafted complexes toward alkane metathesis

Journal of the American Chemical Society

Volumn 126, Issue 41, 2004, Pages 13391-13399

  Le Roux, Erwan ^a   Chabanas, Mathieu ^a   Baudouin, Anne ^a   De Mallmann, Aimery ^a   Copéret, Christophe ^a   Quadrelli, E Alessandra ^a   Thivolle Cazat, Jean ^a   Basset, Jean Marie ^a   Lukens, Wayne ^b   Lesage, Anne ^c,e   Emsley, Lyndon ^c,e   Sunley, Glenn J ^d,f  

^a UMR 5265   (France)

^b LAWRENCE BERKELEY NATIONAL LABORATORY   (United States)

^c UNIVERSITÉ DE LYON   (France)

^d BP EXPLORATION   (United Kingdom)

^e Laboratoire de Chimie Organique   (France)

^f ENS Lyon ^*

Author keywords

[No Author keywords available]

Indexed keywords

COUPLING CONSTANTS; LIGANDS; METALLOCYCLOBUTANE;

CATALYSTS; CHEMICAL BONDS; COMPLEXATION; GRAFTING (CHEMICAL); NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PARAFFINS; REACTION KINETICS; SILICA;

TANTALUM COMPOUNDS;

ALKANE; CYCLOBUTANE; METALLOCYCLOBUTANE; SILICON DIOXIDE; UNCLASSIFIED DRUG;

ARTICLE; CATALYST; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; ELECTROPHORESIS; HYDROXYLATION; MOLECULAR INTERACTION; MOLECULAR STABILITY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; REACTION ANALYSIS; RING CLOSING METATHESIS; SOLID STATE; STRUCTURE ANALYSIS;

EID: 6344261563     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja046486r     Document Type: Article

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