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40
-
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0011086245
-
-
note
-
The hydroxyl region of the IR spectrum is broad and muted, preventing a satisfactory analysis.
-
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41
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0000747729
-
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43
-
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0011133974
-
-
note
-
2) is calculated by a difference file technique. Comparing the Debye-Waller factor of the sample and the reference material allows negative Debye-Waller factor values for samples with higher order than the reference material and positive Debye-Waller factor values for samples less ordered than the reference material.
-
-
-
-
44
-
-
0011133975
-
-
note
-
The distance stated for this contribution may be spuriously short as a consequence of multiple scattering effects that were not taken into account by the reference file used. Since the assignment of this nonbonding shell, which is located far from the absorber (Ir) atom compared to the shells (Ir-Ir and Ir-support) of interest, is tentative and its exact geometry relative to the absorber atom ill-defined, no attempt was made to correct for the influence of multiple scattering.
-
-
-
-
46
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-
0000209196
-
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Kawi, S.; Chang, J.-R.; Gates, B.C. J. Phys. Chem. 1993, 97, 5375.
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49
-
-
0011144940
-
-
note
-
2 treatments.
-
-
-
-
50
-
-
0011106306
-
-
note
-
Another possibility is that this Ir-C contribution arises from some hydrocarbon formed during the decarbonylation process.
-
-
-
-
51
-
-
0011080836
-
-
note
-
The aggregation of the clusters on the surface takes place at temperatures much less than the melting temperature of the clusters, estimated roughly as 0.3 × the melting temperature of the bulk iridium, or about 735 °C.
-
-
-
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52
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5644303009
-
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33751500500
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60
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0001165421
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62
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0011082564
-
-
note
-
4, which results in trace chlorides in the oxide. The manufacturer reported Cl concentrations to be less than a few parts per million.
-
-
-
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63
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0001011282
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Psaro, R.; Dossi, C.; Fusi, A.; Della Pergola, R.; Garlaschelli, L.; Roberto, D.; Sordelli, L.; Ugo, R. J. Chem. Soc., Faraday Trans., 1992, 88, 369.
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64
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0001373975
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Alexeev, O.; Panjabi, G.; Gates, B.C. J. Catal. 1998, 173, 196.
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-
65
-
-
0011146285
-
-
note
-
18, which implies that the clusters occupy about 0.3% of the total surface area, with an average edge-to-edge distance between clusters of roughly 30 Å.
-
-
-
-
67
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33947093716
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Smith, A.K.; Theolier, A.; Basset, J.-M.; Ugo, R.; Commereuc, D.; Chauvin, Y. J. Am. Chem. Soc. 1978, 100, 2590.
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0032818057
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Panjabi, G.1
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0033877427
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5C clusters on MgO demonstrate that bonding at cation defect sites is an order of magnitude stronger than bonding at the defect-free (001)surface of MgO (Goellner, J.F.; Neyman, K.N.; Mayer, M.; Nörtemann, F. Gates, B.C.; Rösch, N. Langmuir 2000, 16, 2736).
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Goellner, J.F.1
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Rösch, N.6
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