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Volumn 38, Issue 13-14, 1999, Pages 1952-1955

Metathesis of alkanes: Evidence for degenerate metathesis of ethane over a silica-supported tantalum hydride prepared by surface organometallic chemistry

Author keywords

Alkanes; C C activation; Metathesis; Surface chemistry; Tantalum

Indexed keywords

ALKANE DERIVATIVE; ETHANE; ORGANOMETALLIC COMPOUND; SILICON DIOXIDE; TANTALUM;

EID: 0033549498     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(sici)1521-3773(19990712)38:13/14<1952::aid-anie1952>3.0.co;2-v     Document Type: Article
Times cited : (55)

References (25)
  • 3
    • 1842367896 scopus 로고    scopus 로고
    • CNRS, FR 9609033
    • V. Vidal, A. Théolier, J. Thivolle-Cazat, J.-M. Basset, Science 1997, 276, 99; CNRS, FR 9609033 [Chem. Abstr. 1998, 128, 129483a].
    • (1998) Chem. Abstr. , vol.128
  • 11
    • 0009679346 scopus 로고
    • h) K. C. Bishop, Chem. Rev. 1976, 76, 461; for C-C bonds in the presence of an activating group:
    • (1976) Chem. Rev. , vol.76 , pp. 461
    • Bishop, K.C.1
  • 14
    • 20044393176 scopus 로고
    • k) J. W. Suggs, C. H. Jun, J. Am. Chem. Soc. 1984, 106, 3054, J. W. Suggs, C. H. Jun, J. Am. Chem. Soc. 1986, 108, 4679; for prearomatic systems:
    • (1984) J. Am. Chem. Soc. , vol.106 , pp. 3054
    • Suggs, J.W.1    Jun, C.H.2
  • 15
    • 0001514931 scopus 로고
    • k) J. W. Suggs, C. H. Jun, J. Am. Chem. Soc. 1984, 106, 3054, J. W. Suggs, C. H. Jun, J. Am. Chem. Soc. 1986, 108, 4679; for prearomatic systems:
    • (1986) J. Am. Chem. Soc. , vol.108 , pp. 4679
    • Suggs, J.W.1    Jun, C.H.2
  • 21
    • 85087234980 scopus 로고    scopus 로고
    • note
    • 3 group in 3 has equal probability of being labeled or unlabeled.
  • 22
    • 0344501620 scopus 로고    scopus 로고
    • note
    • In a batch reactor, secondary reactions between unlabeled and dilabeled ethanes and 3 can occur; the statistical 1:2:1 distribution of unlabeled, monolabeled, and dilabeled molecules is not affected by such a process. Consequently, the value calculated for the ratio of rates of degenerate/productive metathesis is underestimated.
  • 24
    • 0344932586 scopus 로고    scopus 로고
    • Catalytic activation and functionalisation of light alkanes: Advances and challenges
    • b) "Catalytic Activation and Functionalisation of Light Alkanes: Advances and Challenges": G. P. Niccolai, J.-M. Basset, NATO ASI Ser. Ser. C 1998, 44;
    • (1998) NATO ASI Ser. Ser. C , vol.44
    • Niccolai, G.P.1    Basset, J.-M.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.