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Volumn 42, Issue 12, 2003, Pages 1391-1394

Oxidation of supported rhodium clusters by support hydroxy groups

Author keywords

Density functional calculations; Rhodium; Supported catalysts; Surface chemistry; Zeolites

Indexed keywords

ATOMS; HYDROGEN; OXIDATION; PROTONS;

EID: 0038572592     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200390357     Document Type: Article
Times cited : (105)

References (38)
  • 13
    • 0345665141 scopus 로고    scopus 로고
    • note
    • [5].
  • 22
    • 33847087851 scopus 로고
    • and references therein
    • B. K. Teo, Acc. Chem. Res. 1980, 13, 412, and references therein.
    • (1980) Acc. Chem. Res. , vol.13 , pp. 412
    • Teo, B.K.1
  • 23
    • 0344370440 scopus 로고    scopus 로고
    • note
    • 6 cluster in the gas phase, separated from a neutral zeolite fragment.
  • 24
    • 0344802283 scopus 로고    scopus 로고
    • note
    • 6 cluster in the gas phase. A positive value of ΔE(Rh3d) corresponds to a stabilization of Rh3d levels.
  • 25
    • 0345665137 scopus 로고    scopus 로고
    • note
    • [7c]
  • 27
    • 0345233141 scopus 로고    scopus 로고
    • note
    • 6(3H)/Zeo that corresponds to the experimentally observed species, as discussed above, ref. [6].
  • 38
    • 0344802282 scopus 로고    scopus 로고
    • note
    • The question arises as to whether sufficient cycles of pumping would remove all the support OH groups and ultimately prevent reverse spillover, but it is also questionable whether this can be done successfully without sintering the metal.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.