Gauging the relative oxidative powers of compound I, ferric-hydroperoxide, and the ferric-hydrogen peroxide species of cytochrome P450 toward C-H hydroxylation of a radical clock substrate

Journal of the American Chemical Society

Volumn 128, Issue 2, 2006, Pages 473-484

  Derat, Etienne ^a   Kumar, Devesh ^a   Hirao, Hajime ^a   Shaik, Sason ^a  

^a HEBREW UNIVERSITY OF JERUSALEM   (Israel)

Author keywords

[No Author keywords available]

Indexed keywords

ENZYMES; HYDROXYLATION; ISOTOPES; OXIDATION; PORPHYRINS; PROBABILITY DENSITY FUNCTION;

CYTOCHROME; OXIDANTS; SUBSTRATE OXIDATION;

IRON COMPOUNDS;

ALCOHOL; CYTOCHROME P450; FERRIC HYDROGEN PEROXIDE; FERRIC HYDROXIDE; HYDROGEN PEROXIDE; IRON DERIVATIVE; ISOTOPE; PORPHYRIN; REAGENT; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; DENSITY FUNCTIONAL THEORY; ENZYME KINETICS; ENZYME MECHANISM; ENZYME SUBSTRATE; HYDROXYLATION; OXIDATION; REACTION ANALYSIS;

EID: 31544475727     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja056328f     Document Type: Article

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