Oxygen- and temperature-dependent kinetic isotope effects in choline oxidase: Correlating reversible hydride transfer with environmentally enhanced tunneling

Journal of the American Chemical Society

Volumn 127, Issue 50, 2005, Pages 17954-17961

  Fant, Fan ^a   Gadda, Giovanni ^a  

^a GEORGIA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDES; CONCENTRATION (PROCESS); ELECTRON TUNNELING; ENZYMES; HYDRIDES; OXIDATION; OXYGEN; QUANTUM THEORY; REACTION KINETICS;

GLYCINE BETAINE; KINETIC ISOTOPE EFFECTS; OXYGEN CONCENTRATION; REACTION COORDINATE;

ISOTOPES;

ALDEHYDE DERIVATIVE; BETAINE; CHOLINE; CHOLINE OXIDASE; DEUTERIUM; ISOTOPE; OXYGEN;

ARTICLE; CONCENTRATION (PARAMETERS); ELECTRON TRANSPORT; ENTHALPY; ENZYME KINETICS; ENZYME MECHANISM; OXIDATION; PARTITION COEFFICIENT; PH; PKA; QUANTUM MECHANICS; REACTION ANALYSIS; TEMPERATURE DEPENDENCE; VIBRATION;

ALCOHOL OXIDOREDUCTASES; CATALYSIS; CHOLINE; DEUTERIUM EXCHANGE MEASUREMENT; HYDROGEN-ION CONCENTRATION; KINETICS; OXYGEN; TEMPERATURE;

EID: 29344449107     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0560377     Document Type: Article

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