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Polymer topology refers to the geometric arrangement of monomeric units on a macromolecule (e.g., linear, cyclic, hyperbranched, or dendritic). Other terms, such as microstructure and architecture, are also used frequently in the literature to describe polymers with different structures. Microstructure is usually used to describe polymer local structures, which are not sufficient for characterizing the macromolecular global topology. The term polymer architecture has been used very broadly to describe many types of polymer structures, including star, block, and graft polymers, polymers with various branching forms, and polymers with different tacticities. In this article, the term topology has been chosen to describe polymers that are made of the same building blocks but in different geometric arrangements.
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