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This approach was first accomplished by Ziegler in his early work when nickel was introduced with titanium, either purposely or through autoclave corrosion as part of the investigation of the "Aufbau" reaction. The nickel dimerized ethylene to butene, while the titanium incorporated it at low levels yielding polyethylenes with low levels of ethyl branches. We have been told that this work appears in early notebooks from the Ziegler laboratory, but we have been unable to find a reference in the open literature.
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