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We describe here a discrete olefin-hydride intermediate; however, β-H transfer may occur through a concerted process with an olefin-hydride-like transition state, as suggested by Ziegler et al.: (a) Deng, L.; Margl, P.; Ziegler, T. J. Am. Chem. Soc. 1997, 119, 1094-1100 (b) Deng, L.; Woo, T. K.; Cavallo, L.; Margl, P. M.; Ziegler, T. J. Am. Chem. Soc. 1997, 119, 6177-6186.
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0343982060
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note
-
3-Br can result in explosions. This material is commercially available from Boulder Scientific.
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85
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0343110057
-
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note
-
2O in the sample. The correct chemical shift is δ 16.7 (9 peaks, J = 1.5 Hz, IH).
-
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87
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