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note
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The transient absorption spectrum of 1 was originally recorded in a point-by-point fashion and reported in ref 26. The spectra shown in Figure 7b have since been recorded using the YAG/OPO/ICCD apparatus installed at the University of Melbourne and are included for comparison and reference purposes.
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65
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0011306786
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note
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Experiment undertaken in collaboration with Prof. Graham Fleming and Dr. Greg Scholes at the University of California, Berkeley, USA. A two exponential fit of a fluorescence upconversion decay profile gave 880 fs (42%) and 80 ps (58%) components.
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67
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0011268668
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note
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All geometry optimisations were carried out on a less substituted analogue of 2, in which the four 3,5-di-tert-butylphenyl substituents of the zinc porphyrin and the two methoxy substituents of the naphthalene are replaced by hydrogen atoms.
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81
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note
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60 separation is most likely too great for significant PET from these triplet states, but conversion to the collapsed conformation is the source of the quenched triplet state lifetimes of 2 in both toluene and benzonitrile.
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