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The abbreviation hydrazine will be used for this compound throughout this paper.
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34
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0011385895
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Pure I was also tried but gave highly irreproducible results.
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36
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0011429487
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Shorter reaction times (16 and 24 h) gave smaller changes in the water contact angles, which suggests that there were still phthalimide groups present, as they are more hydrophobic than amino groups. The 16 h sample indeed still showed a small C=O peak in the IR spectrum. Much longer reaction times (up to 7 days) did not give a further decrease in the contact angles. These results indicate that this reaction time of 40-48 h is required for complete removal of the phthalimide groups. Heating the solution, to speed up the reaction, seemed to cause some damage to the edges of the Si substrate. At room temperature, no damage to these edges occurs.
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37
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0011441548
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Reaction times of only a few (2-5) hours seemed insufficient to completely remove the acetamide groups (contact angle measurements). A reaction time of 40 h gave contact angles that were comparable to the 20 h samples: they differed by only 1-2°, which is within the experimental error. Only minor changes in the water contact angles of the acetamide-terminated monolayers (decrease of ∼5°) were observed if 1 M HCl was used.
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