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note
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One of the reviewers suggested that the odd behavior of anisole-the only oxygenated solvent in the series investigated-could also be the result of a higher residual water content. As traces of residual water are indeed an important factor in the modification of hydrogen-terminated silicon surfaces this explanation can currently not be excluded, although distilled anisole was dried over NaOH prior to use.
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0343908664
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note
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3.
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0343908665
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note
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Although the free volume of tert-butylbenzene is larger than that of mesitylene, the diameter of the molecule with respect to that of the phenyl ring is only slightly increased by the tert-butyl group. This group has a diameter of approximately 4.4 Å, which is similar to the diameter of approximately 4.3 Å of a phenyl ring. As mesitylene has a diameter of 5.4 Å, this difference in the width of the two molecules, combined with the presence of a relatively large alkyl group in tert-butylbenzene, may explain the observed differences between the two solvents at lower 1-hexadecene concentrations.
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