Basal-Plane Ligand Functionalization on Semiconducting 2H-MoS2 Monolayers

ACS Applied Materials and Interfaces

Volumn 9, Issue 14, 2017, Pages 12734-12742

  Ding, Qi ^a   Czech, Kyle J ^a   Zhao, Yuzhou ^a   Zhai, Jianyuan ^a   Hamers, Robert J ^a   Wright, John C ^a   Jin, Song ^a  

^a UNIVERSITY OF WISCONSIN MADISON   (United States)

Author keywords

basal plane; ligand functionalization; monolayer; MoS2; sulfur vacancy

Indexed keywords

CHEMICAL VAPOR DEPOSITION; LIGANDS; MOLECULES; MONOLAYERS; SEMICONDUCTOR QUANTUM DOTS; SULFUR; SURFACE CHEMISTRY; VACANCIES;

BASAL PLANES; CATALYTIC APPLICATIONS; CHEMICAL VAPOR DEPOSITIONS (CVD); COVALENT FUNCTIONALIZATIONS; LIGAND FUNCTIONALIZATION; PHOTOLUMINESCENCE RESPONSE; SULFUR VACANCIES; TWO-DIMENSIONAL MATERIALS;

MOLYBDENUM COMPOUNDS;

EID: 85017407463     PISSN: 19448244     EISSN: 19448252     Source Type: Journal    
DOI: 10.1021/acsami.7b01262     Document Type: Article

References (58)

1. Wang, Q. H.; Kalantar-Zadeh, K.; Kis, A.; Coleman, J. N.; Strano, M. S. Electronics and Optoelectronics of Two-Dimensional Transition Metal Dichalcogenides Nat. Nanotechnol. 2012, 7, 699-712 10.1038/nnano.2012.193
2. Chhowalla, M.; Shin, H. S.; Eda, G.; Li, L. J.; Loh, K. P.; Zhang, H. The Chemistry of Two-Dimensional Layered Transition Metal Dichalcogenide Nanosheets Nat. Chem. 2013, 5, 263-275 10.1038/nchem.1589
3. Xu, M. S.; Liang, T.; Shi, M. M.; Chen, H. Z. Graphene-Like Two-Dimensional Materials Chem. Rev. 2013, 113, 3766-3798 10.1021/cr300263a
4. Butler, S. Z.; Hollen, S. M.; Cao, L. Y.; Cui, Y.; Gupta, J. A.; Gutierrez, H. R.; Heinz, T. F.; Hong, S. S.; Huang, J. X.; Ismach, A. F.; Johnston-Halperin, E.; Kuno, M.; Plashnitsa, V. V.; Robinson, R. D.; Ruoff, R. S.; Salahuddin, S.; Shan, J.; Shi, L.; Spencer, M. G.; Terrones, M.; Windl, W.; Goldberger, J. E. Progress, Challenges, and Opportunities in Two-Dimensional Materials Beyond Graphene ACS Nano 2013, 7, 2898-2926 10.1021/nn400280c
5. 2 Nanosheets J. Am. Chem. Soc. 2013, 135, 10274-10277 10.1021/ja404523s
6. Benck, J. D.; Hellstern, T. R.; Kibsgaard, J.; Chakthranont, P.; Jaramillo, T. F. Catalyzing the Hydrogen Evolution Reaction (HER) with Molybdenum Sulfide Nanomaterials ACS Catal. 2014, 4, 3957-3971 10.1021/cs500923c
7. Mattheiss, L. F. Band Structures of Transition-Metal-Dichalcogenide Layer Compounds Phys. Rev. B 1973, 8, 3719-3740 10.1103/PhysRevB.8.3719
8. 2: A New Direct-Gap Semiconductor Phys. Rev. Lett. 2010, 105, 136805 10.1103/PhysRevLett.105.136805
9. 2 Via Chemical Doping Nano Lett. 2013, 13, 5944-5948 10.1021/nl403036h
10. 2 Phototransistors ACS Nano 2012, 6, 74-80 10.1021/nn2024557
11. 2 Nanosheet Phototransistors with Thickness-Modulated Optical Energy Gap Nano Lett. 2012, 12, 3695-3700 10.1021/nl301485q
12. Wu, S. F.; Buckley, S.; Schaibley, J. R.; Feng, L. F.; Yan, J. Q.; Mandrus, D. G.; Hatami, F.; Yao, W.; Vuckovic, J.; Majumdar, A.; Xu, X. D. Monolayer Semiconductor Nanocavity Lasers with Ultralow Thresholds Nature 2015, 520, 69-72 10.1038/nature14290
13. 2 Transistors Nat. Nanotechnol. 2011, 6, 147-150 10.1038/nnano.2010.279
14. 2 Mater. Today 2016, 19, 140-145 10.1016/j.mattod.2015.08.019
15. Chen, X.; McDonald, A. R. Functionalization of Two-Dimensional Transition-Metal Dichalcogenides Adv. Mater. 2016, 28, 5738-46 10.1002/adma.201505345
16. 2 Honeycomb Structures J. Phys. Chem. C 2011, 115, 13303-13311 10.1021/jp2000442
17. 2Monolayer by Covalent Functionalization Chem. Mater. 2015, 27, 3743-3748 10.1021/acs.chemmater.5b00986
18. 2 Via Highly Stable Thiol-Based Molecular Chemisorption ACS Nano 2015, 9, 12115-12123 10.1021/acsnano.5b05173
19. 2 with Sulfur Vacancy Passivation by Treatment with Alkanethiol Molecules ACS Nano 2015, 9, 8044-8053 10.1021/acsnano.5b04400
20. 2 J. Am. Chem. Soc. 2013, 135, 4584-4587 10.1021/ja310929s
21. 2 Nano-Sheets for Combined Photothermal and Chemotherapy of Cancer Adv. Mater. 2014, 26, 3433-3440 10.1002/adma.201305256
22. 2 Nanocatalysts Science 2007, 317, 100-102 10.1126/science.1141483
23. 2 Photoanodes J. Am. Chem. Soc. 1981, 103, 1279-1281 10.1021/ja00395a076
24. 2 Electrochemical Sensors Anal. Chem. 2014, 86, 12064-12069 10.1021/ac5027786
25. 2 Nanosheets by an Organosulfur Reaction Chem.-Eur. J. 2015, 21, 15583-15588 10.1002/chem.201502303
26. 2 Nano Lett. 2014, 14, 5941-5947 10.1021/nl502906a
27. 2 Angew. Chem., Int. Ed. 2015, 54, 2638-2642 10.1002/anie.201409412
28. 2 through Surface Functionalization Adv. Mater. 2015, 27, 6225-6229 10.1002/adma.201503163
29. Voiry, D.; Goswami, A.; Kappera, R.; Silva, C. D. C. E.; Kaplan, D.; Fujita, T.; Chen, M. W.; Asefa, T.; Chhowalla, M. Covalent Functionalization of Monolayered Transition Metal Dichalcogenides by Phase Engineering Nat. Chem. 2014, 7, 45-49 10.1038/nchem.2108
30. Knirsch, K. C.; Berner, N. C.; Nerl, H. C.; Cucinotta, C. S.; Gholamvand, Z.; McEvoy, N.; Wang, Z. X.; Abramovic, I.; Vecera, P.; Halik, M.; Sanvito, S.; Duesberg, G. S.; Nicolosi, V.; Hauke, F.; Hirsch, A.; Coleman, J. N.; Backes, C. Basal-Plane Functionalization of Chemically Exfoliated Molybdenum Disulfide by Diazonium Salts ACS Nano 2015, 9, 6018-6030 10.1021/acsnano.5b00965
31. 2 Nanosheets RSC Adv. 2014, 4, 32570-32578 10.1039/C4RA04682J
32. 2: An Ab Initio Local-Density-Functional Study Phys. Rev. Lett. 1998, 80, 1481-1484 10.1103/PhysRevLett.80.1481
33. 2 Nanosheets with Inorganic Nanoparticles J. Mater. Chem. A 2015, 3, 1042-1048 10.1039/C4TA04946B
34. 2 with Poss for Enhancing Thermal, Flame-Retardant and Mechanical Properties in Pva Composites RSC Adv. 2014, 4, 3253-3262 10.1039/C3RA45911J
35. Hong, J. H.; Hu, Z. X.; Probert, M.; Li, K.; Lv, D. H.; Yang, X. N.; Gu, L.; Mao, N. N.; Feng, Q. L.; Xie, L. M.; Zhang, J.; Wu, D. Z.; Zhang, Z. Y.; Jin, C. H.; Ji, W.; Zhang, X. X.; Yuan, J.; Zhang, Z. Exploring Atomic Defects in Molybdenum Disulphide Monolayers Nat. Commun. 2015, 6, 6293 10.1038/ncomms7293
36. Qiu, H.; Xu, T.; Wang, Z. L.; Ren, W.; Nan, H. Y.; Ni, Z. H.; Chen, Q.; Yuan, S. J.; Miao, F.; Song, F. Q.; Long, G.; Shi, Y.; Sun, L. T.; Wang, J. L.; Wang, X. R. Hopping Transport through Defect-Induced Localized States in Molybdenum Disulphide Nat. Commun. 2013, 4, 2642 10.1038/ncomms3642
37. Zhou, W.; Zou, X. L.; Najmaei, S.; Liu, Z.; Shi, Y. M.; Kong, J.; Lou, J.; Ajayan, P. M.; Yakobson, B. I.; Idrobo, J. C. Intrinsic Structural Defects in Monolayer Molybdenum Disulfide Nano Lett. 2013, 13, 2615-2622 10.1021/nl4007479
38. 2 with Sulfur Vacancies: Structure and Catalytic Application J. Phys. Chem. C 2014, 118, 5346-5351 10.1021/jp411256g
39. Yu, Z. H.; Pan, Y. M.; Shen, Y. T.; Wang, Z. L.; Ong, Z. Y.; Xu, T.; Xin, R.; Pan, L. J.; Wang, B. G.; Sun, L. T.; Wang, J. L.; Zhang, G.; Zhang, Y. W.; Shi, Y.; Wang, X. R. Towards Intrinsic Charge Transport in Monolayer Molybdenum Disulfide by Defect and Interface Engineering Nat. Commun. 2014, 5, 5290 10.1038/ncomms6290
40. 2: Evolution of Atomic Structure under Electron Irradiation Phys. Rev. B: Condens. Matter Mater. Phys. 2013, 88, 035301 10.1103/PhysRevB.88.035301
41. Najmaei, S.; Liu, Z.; Zhou, W.; Zou, X. L.; Shi, G.; Lei, S. D.; Yakobson, B. I.; Idrobo, J. C.; Ajayan, P. M.; Lou, J. Vapour Phase Growth and Grain Boundary Structure of Molybdenum Disulphide Atomic Layers Nat. Mater. 2013, 12, 754-759 10.1038/nmat3673
42. Castner, D. G.; Hinds, K.; Grainger, D. W. X-Ray Photoelectron Spectroscopy Sulfur 2p Study of Organic Thiol and Disulfide Binding Interactions with Gold Surfaces Langmuir 1996, 12, 5083-5086 10.1021/la960465w
43. Hsu, T. M.; Lee, J. S.; Hwang, H. L. Photoreflectance of Sulfur-Annealed Copper Indium Disulfide J. Appl. Phys. 1990, 68, 283-287 10.1063/1.347128
44. Yin, Y.; Han, J.; Zhang, Y.; Zhang, X.; Xu, P.; Yuan, Q.; Samad, L.; Wang, X.; Wang, Y.; Zhang, Z.; Zhang, P.; Cao, X.; Song, B.; Jin, S. Contributions of Phase, Sulfur Vacancies, and Edges to the Hydrogen Evolution Reaction Catalytic Activity of Porous Molybdenum Disulfide Nanosheets J. Am. Chem. Soc. 2016, 138, 7965-7972 10.1021/jacs.6b03714
45. 2 Nanosheets J. Am. Chem. Soc. 2015, 137, 2622-2627 10.1021/ja5120908
46. 2 by Hydrohalic Acid Treatment ACS Nano 2016, 10, 1454-1461 10.1021/acsnano.5b06960
47. 2 Science 2015, 350, 1065-1068 10.1126/science.aad2114
48. 2 J. Am. Chem. Soc. 2014, 136, 8504-8507 10.1021/ja5025673
49. Y (Q = S, Se) Catalysts on Si Micropyramids Adv. Mater. 2015, 27, 6511-6518 10.1002/adma.201501884
50. 2 and Related Compounds Chem. 2016, 1, 699-726 10.1016/j.chempr.2016.10.007
51. 2 Basal Planes for Hydrogen Evolution through the Formation of Strained Sulphur Vacancies Nat. Mater. 2015, 15, 48-53 10.1038/nmat4465
52. Selinsky, R. S.; Ding, Q.; Faber, M. S.; Wright, J. C.; Jin, S. Quantum Dot Nanoscale Heterostructures for Solar Energy Conversion Chem. Soc. Rev. 2013, 42, 2963-2985 10.1039/C2CS35374A
53. Watson, D. F. Linker-Assisted Assembly and Interfacial Electron-Transfer Reactivity of Quantum Dot-Substrate Architectures J. Phys. Chem. Lett. 2010, 1, 2299-2309 10.1021/jz100571u
54. Kongkanand, A.; Tvrdy, K.; Takechi, K.; Kuno, M.; Kamat, P. V. Quantum Dot Solar Cells. Tuning Photoresponse through Size and Shape Control of CdSe-TiO2 Architecture J. Am. Chem. Soc. 2008, 130, 4007-4015 10.1021/ja0782706
55. Wehrenberg, B. L.; Wang, C. J.; Guyot-Sionnest, P. Interband and Intraband Optical Studies of PbSe Colloidal Quantum Dots J. Phys. Chem. B 2002, 106, 10634-10640 10.1021/jp021187e
56. 2 Nanosheets and Their near-Infrared Photoresponse Adv. Funct. Mater. 2014, 24, 5798 10.1002/adfm.201400330
57. 2 Vertical Heterostructures Via Van Der Waals Epitaxy ACS Nano 2016, 10, 7039-7046 10.1021/acsnano.6b03112
58. Jariwala, D.; Marks, T. J.; Hersam, M. C. Mixed-Dimensional Van Der Waals Heterostructures Nat. Mater. 2016, 16, 170-181 10.1038/nmat4703