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Volumn 20, Issue 39, 2014, Pages 12544-12552

Small Molecule Activation by POCsp 3OP-Nickel Complexes

Author keywords

Arbuzov rearrangement; migratory insertion; pincer complexes; reductive elimination; small molecule activation

Indexed keywords

CARBON DIOXIDE; CARBONYLATION; CARBOXYLATION; CHEMICAL ACTIVATION; LIGANDS; MOLECULES; NITROGEN COMPOUNDS;

EID: 84982293308     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201402933     Document Type: Article
Times cited : (26)

References (90)
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    • For recent reviews on catalytic activation of small molecules, see
    • For recent reviews on catalytic activation of small molecules, see:
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    • For selected examples of small molecule activation mediated by metal complexes featuring multi-dentate ligands, see
    • For selected examples of small molecule activation mediated by metal complexes featuring multi-dentate ligands, see:
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    • 84868514070 scopus 로고    scopus 로고
    • (Eds., G. van Koten, D. Milstein, Springer-Verlag, Heidelberg, 40
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    • Zargarian, D.1    Castonguay, A.2    Spasyuk, D.M.3
  • 42
    • 85099670743 scopus 로고    scopus 로고
    • Note, however, that Ni, complexes are accessible with POCN-type ligands based on an aromatic backbone
    • III complexes are accessible with POCN-type ligands based on an aromatic backbone:
  • 48
    • 85099672102 scopus 로고    scopus 로고
    • See, for example, the following reports on pincer systems featuring flexible backbones (a–c)a report on a PC, P system (d) that displays an interesting and reversible non-innocent behavior
    • sp 2P system (d) that displays an interesting and reversible non-innocent behavior:
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    • 17144397739 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2005, 44, 1709–1711.
    • (2005) Angew. Chem. Int. Ed. , vol.44 , pp. 1709-1711
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    • Angew. Chem. Int. Ed. 2014, 53, 3218–3222.
    • (2014) Angew. Chem. Int. Ed. , vol.53 , pp. 3218-3222
  • 56
    • 84982246032 scopus 로고    scopus 로고
    • CCDC-939956 (Ni-NHAr), CCDC-975283 (Ni-OC(O)NHAr), CCDC-975282 (Ni-C(O)NHAr), CCDC-936884 CCDC-936885 (2), CCDC-936525 (Ni-OP(O)R,)CCDC-939954 (4) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via
    • CCDC-939956 (Ni-NHAr), CCDC-975283 (Ni-OC(O)NHAr), CCDC-975282 (Ni-C(O)NHAr), CCDC-936884 (1), CCDC-936885 (2), CCDC-936525 (Ni-OP(O)R2), and CCDC-939954 (4) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
    • , Issue.1
  • 70
    • 85099671788 scopus 로고    scopus 로고
    • This signal falls in the usual range for complexes of the type (POC, OP)NiY with Y representing an anionic ligand based on an electronegative atom such as O or N
    • sp 3OP)NiY with Y representing an anionic ligand based on an electronegative atom such as O or N.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.